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dc.contributor.author Brown, TJ
dc.contributor.author Sugie, A
dc.contributor.author Dickens, MG
dc.contributor.author Widenhoefer, RA
dc.date.accessioned 2011-06-21T17:27:12Z
dc.date.issued 2010-10-11
dc.identifier.citation Organometallics, 2010, 29 (19), pp. 4207 - 4209
dc.identifier.issn 0276-7333
dc.identifier.uri http://hdl.handle.net/10161/4112
dc.description.abstract The cationic gold π-allene complex {[P(t-Bu)2o-biphenyl] Au[η2-H2C=C=C(CH3)2]} +SbF6- was isolated in 98% yield from reaction of 3-methyl-1,2-butadiene with a mixture of [P(t-Bu)2o-biphenyl]AuCl and AgSbF6 and was characterized by X-ray crystallography and variable-temperature NMR spectroscopy. These studies revealed preferential binding of gold to the less substituted C=C bond of the allene in both the solid state and solution and also revealed fluxional behavior consistent with π-face exchange of the allene ligand via an η1-C2 allene intermediate or transition state. © 2010 American Chemical Society.
dc.format.extent 4207 - 4209
dc.language.iso en_US en_US
dc.relation.ispartof Organometallics
dc.relation.isversionof 10.1021/om100688t
dc.title Solid-state and dynamic solution behavior of a cationic, two-coordinate gold(I) π-allene complex
dc.title.alternative en_US
dc.type Journal Article
dc.description.version Version of Record en_US
duke.date.pubdate 2010-10-11 en_US
duke.description.endpage 4209 en_US
duke.description.issue 19 en_US
duke.description.startpage 4207 en_US
duke.description.volume 29 en_US
dc.relation.journal Organometallics en_US
pubs.issue 19
pubs.organisational-group /Duke
pubs.organisational-group /Duke/Trinity College of Arts & Sciences
pubs.organisational-group /Duke/Trinity College of Arts & Sciences/Chemistry
pubs.publication-status Published
pubs.volume 29
dc.identifier.eissn 1520-6041

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