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dc.contributor.author Lewerenz, HJ
dc.contributor.author Heine, C
dc.contributor.author Skorupska, K
dc.contributor.author Szabo, N
dc.contributor.author Hannappel, T
dc.contributor.author Vo-Dinh, T
dc.contributor.author Campbell, SA
dc.contributor.author Klemm, HW
dc.contributor.author Muñoz, AG
dc.date.accessioned 2011-06-21T17:27:12Z
dc.date.issued 2010-06-11
dc.identifier.citation Energy and Environmental Science, 2010, 3 (6), pp. 748 - 760
dc.identifier.issn 1754-5692
dc.identifier.uri http://hdl.handle.net/10161/4115
dc.description.abstract An overview on processes that are relevant in light-induced fuel generation, such as water photoelectrolysis or carbon dioxide reduction, is given. Considered processes encompass the photophysics of light absorption, excitation energy transfer to catalytically active sites and interfacial reactions at the catalyst/solution phase boundary. The two major routes envisaged for realization of photoelectrocatalytic systems, e.g. bio-inspired single photon catalysis and multiple photon inorganic or hybrid tandem cells, are outlined. For development of efficient tandem cell structures that are based on non-oxidic semiconductors, stabilization strategies are presented. Physical surface passivation is described using the recently introduced nanoemitter concept which is also applicable in photovoltaic (solid state or electrochemical) solar cells and first results with p-Si and p-InP thin films are presented. Solar-to-hydrogen efficiencies reach 12.1% for homoepitaxial InP thin films covered with Rh nanoislands. In the pursuit to develop biologically inspired systems, enzyme adsorption onto electrochemically nanostructured silicon surfaces is presented and tapping mode atomic force microscopy images of heterodimeric enzymes are shown. An outlook towards future envisaged systems is given. © 2010 The Royal Society of Chemistry.
dc.format.extent 748 - 760
dc.language.iso en_US en_US
dc.relation.ispartof Energy and Environmental Science
dc.relation.isversionof 10.1039/b915922n
dc.title Photoelectrocatalysis: Principles, nanoemitter applications and routes to bio-inspired systems
dc.title.alternative en_US
dc.type Journal Article
dc.description.version Version of Record en_US
duke.date.pubdate 2010-6-0 en_US
duke.description.endpage 760 en_US
duke.description.issue 6 en_US
duke.description.startpage 748 en_US
duke.description.volume 3 en_US
dc.relation.journal Energy & Environmental Science en_US
pubs.issue 6
pubs.organisational-group /Duke
pubs.organisational-group /Duke/Institutes and Provost's Academic Units
pubs.organisational-group /Duke/Institutes and Provost's Academic Units/Initiatives
pubs.organisational-group /Duke/Institutes and Provost's Academic Units/Initiatives/Energy Initiative
pubs.organisational-group /Duke/Pratt School of Engineering
pubs.organisational-group /Duke/Pratt School of Engineering/Biomedical Engineering
pubs.organisational-group /Duke/School of Medicine
pubs.organisational-group /Duke/School of Medicine/Institutes and Centers
pubs.organisational-group /Duke/School of Medicine/Institutes and Centers/Duke Cancer Institute
pubs.organisational-group /Duke/Trinity College of Arts & Sciences
pubs.organisational-group /Duke/Trinity College of Arts & Sciences/Chemistry
pubs.publication-status Published
pubs.volume 3
dc.identifier.eissn 1754-5706

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