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Direct carbon-carbon bond formation via soft enolization: aldol addition of alpha-halogenated thioesters

DukeSpace

Direct carbon-carbon bond formation via soft enolization: aldol addition of alpha-halogenated thioesters

Yost, Julianne M. ; Alfie, Rachel J. ; Tarsis, Emily ; Chong, Insun ; Coltart, Dr Don
URI: http://hdl.handle.net/10161/4130
Published Version: doi:10.1039/c0cc02345k
Date: 2011

Abstract:

alpha-Halo thioesters undergo soft enolization and syn-selective direct aldol addition to aldehydes in the presence of MgBr2 center dot OEt2 and i-Pr2NEt to produce alpha-halo-beta-hydroxy thioesters.

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