Wang, ZABienvenu, DJMann, PJHoering, KAPoulsen, JRSpencer, RGMHolmes, RM2018-11-022018-11-022013-02-160094-82761944-8007https://hdl.handle.net/10161/17627Seasonal variations in inorganic carbon chemistry and associated fluxes from the Congo River were investigated at Brazzaville-Kinshasa. Small seasonal variation in dissolved inorganic carbon (DIC) was found in contrast with discharge-correlated changes in pH, total alkalinity (TA), carbonate species, and dissolved organic carbon (DOC). DIC was almost always greater than TA due to the importance of CO<inf>2</inf>*, the sum of dissolved CO<inf>2</inf> and carbonic acid, as a result of low pH. Organic acids in DOC contributed 11-61% of TA and had a strong titration effect on water pH and carbonate speciation. The CO<inf>2</inf>* and bicarbonate fluxes accounted for ~57% and 43% of the DIC flux, respectively. Congo River surface water released CO<inf>2</inf> at a rate of ~109 mol m^-2 yr^-1. The basin-wide DIC yield was ~8.84 × 10⁴ mol km^-2 yr^-1. The discharge normalized DIC flux to the ocean amounted to 3.11 × 10¹¹ mol yr^-1. The DOC titration effect on the inorganic carbon system may also be important on a global scale for regulating carbon fluxes in rivers. Key Points The carbonate chemistry near the Congo River mouth is comprehensively studied Organic acids have a titration effect on the inorganic carbon system Surface CO<inf>2</inf> and inorganic carbon fluxes to the ocean are characterized ©2013. American Geophysical Union. All Rights Reserved.Science & TechnologyPhysical SciencesGeosciences, MultidisciplinaryGeologyORGANIC-MATTERAMAZONIAN RIVERSDIOXIDECO2BIOGEOCHEMISTRYESTUARINEELEMENTSWATERSBUDGETBASINJournal article2018-11-02