Browsing by Author "Klein, Emily M"
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Item Open Access A Case Study of GreenToGo in Durham, North Carolina(2019-04-26) DePouw, Heather; Jiao, Yuchen; Marshall, LayneThe goal of the GreenToGo program in Durham, North Carolina is to provide the shared customers of GreenToGo and local Durham restaurants with an environmentally-conscious option for carryout food containers. This report highlights our efforts to identify and address the barriers to implementing GreenToGo reusable to-go containers for both businesses and consumers. We conducted research on consumer behavior and attitudes around green products, interviewed restaurant owners and managers, and surveyed customers to provide insight on opinions and perspectives of the GreenToGo program. Strategy summaries detailed important aspects of the program framework for scaling up the business plan to other community types. The development of program recommendations can be used to support the long-term sustainability of the Durham-based initiative along with its implementation in other locations.Item Open Access A Sustainability Plan for American Tobacco Campus(2011-04-29) Lareau, Courtney; Rankin, Kimberlee; Tucker, BunnyAmerican Tobacco Campus (ATC) Management has committed to understanding the environmental impact of their campus and making strategic improvements, while reducing operational costs. This Masters Project focused on determining ATC’s environmental impacts by collecting baseline data on the three key impact areas designated by ATC Management: energy use, water consumption, and waste generation. Initial reduction goals were then established and strategies were developed to achieve reductions that would help ATC Management make progress toward achieving these goals. Tenant and employee engagement were additional factors considered in strategic initiatives. This Sustainability Plan for American Tobacco Campus represents an initial assessment of ATC’s environmental performance.Item Open Access An Analysis of Sustainability Strategic Planning at Duke University(2012-04-27) Jones, Kelly; Hildenbrand, Jim; Willie, NicholasThis study was conducted in order to inform the sustainability planning process at Duke University and similar institutions of higher education. Through interviews of Duke University Campus Sustainability Committee members and a cost-benefit analysis of Duke’s Climate Action Plan, we evaluated the effectiveness of Duke’s sustainability planning and implementation process. Additionally, we investigated the widely varying sustainability approaches and metrics used by fifteen peer institutions to evaluate their relative merits. In depth interviews were also conducted with Brown University and Yale University staff members for comparison to Duke. Our work resulted in (1) a generic roadmap for universities seeking to develop their own sustainability plan and (2) a list of recommendations to improve upon Duke’s already successful model.Item Open Access AN ANALYSIS OF SUSTAINABILITY STRATEGIC PLANNING AT DUKE UNIVERSITY(2012-04-27) Hildenbrand, Jim; Willie, Nicholas; Jones, KellyThis study was conducted in order to inform the sustainability planning process at Duke University and similar institutions of higher education. Through interviews of Duke University Campus Sustainability Committee members and a cost-benefit analysis of Duke’s Climate Action Plan, we evaluated the effectiveness of Duke’s sustainability planning and implementation process. Additionally, we investigated the widely varying sustainability approaches and metrics used by fifteen peer institutions to evaluate their relative merits. In depth interviews were also conducted with Brown University and Yale University staff members for comparison to Duke. Our work resulted in (1) a generic roadmap for universities seeking to develop their own sustainability plan and (2) a list of recommendations to improve upon Duke’s already successful model.Item Open Access An Analysis of Sustainability Strategic Planning at Duke University(2012-04-27) Hildenbrand, Jim; Jones, Kelly; Willie, NicholasThis study was conducted in order to inform the sustainability planning process at Duke University and similar institutions of higher education. Through interviews of Duke University Campus Sustainability Committee members and a cost-benefit analysis of Duke’s Climate Action Plan, we evaluated the effectiveness of Duke’s sustainability planning and implementation process. Additionally, we investigated the widely varying sustainability approaches and metrics used by fifteen peer institutions to evaluate their relative merits. In depth interviews were also conducted with Brown University and Yale University staff members for comparison to Duke. Our work resulted in (1) a generic roadmap for universities seeking to develop their own sustainability plan and (2) a list of recommendations to improve upon Duke's already successful model.Item Open Access Assessing the Hedging Value of Wind Against Natural Gas Price Volatility(2014-04-25) Inda, Ada; Wu, Jill; Zhou, DanIn recent years, natural gas prices in the U.S. have reached historic lows and utilities have been rapidly replacing coal with gas-fired generation. Natural gas prices are historically volatile, and overreliance on natural gas can lead to high electricity prices in the event of rising fuel costs or price spikes. We examine how utilities can use wind energy from long-term power purchase agreements (PPAs) as a tool to hedge against natural gas price volatility and future environmental regulations. We assess how federal and state policies affect wind’s hedging value, and provide a case study on how utilities in the Southeast are increasingly importing wind from high capacity regions. We quantify wind’s hedging value by comparing the net present value (NPV) of investment costs for a natural gas combined cycle plant with and without wind generation to meet future demand under uncertainty. We use wind prices from the Lawrence Berkeley National Laboratory national wind PPA sample, and analyze six investment options over a 30-year period using the U.S. Energy Information Administration’s (EIA) AEO 2013 natural gas price scenarios with and without carbon tax, and our own scenarios created using Monte Carlo simulation and Random Walk. Assuming a least-cost framework, we find that the utility would only invest in gas generation under the EIA reference scenario. In our model, the utility will have an NPV cost band from $4.7 to $10.1 billion if they do not hedge with wind, whereas if they add 20% wind to their portfolio, the maximum cost will decrease by $774 million if the worst-case gas price scenario were to occur. By procuring wind energy at fixed prices through long-term PPAs, utilities can reduce their exposure to unfavorable cost outcomes, particularly if a carbon tax of $10 per ton or more is enacted.Item Open Access Barriers to Environmental Sustainability Facing Small Businesses in Durham, NC(2010-04-30T14:39:32Z) Hadley, John; Herren, AllisonConventional approaches to implementing environmental practices often rely on assumptions and measures predominantly developed for large corporations. However, small and medium-sized enterprises (SMEs) frequently operate much differently and encounter a variety of barriers to environmental practices that may not exist in the larger corporate arena. This research paper analyzes the barriers small businesses face to implementing environmental measures through interviews with nine companies in the Durham, North Carolina area. The study finds that financial cost is the main barrier, followed by a lack of time to devote to environmental measures, and a lack of knowledge of actions that can be taken. The study concludes with recommendations for regulatory and policy updates, economic incentives, and information resources to help mitigate the environmental barriers facing small businesses in Durham.Item Open Access Environmental Help Desk for Transportation and Warehousing Industries(2013-04-24) Xie, Yilin; Yuan, Yuan; Gelsinger, Taylor; Chou, JosephCompanies today face a variety of challenges and opportunities when considering investing in the environmental sustainability of their business. Compared to large companies, small and medium sized businesses do not have the resources available to leverage for consultants or invest in capital intensive projects. Therefore, Green Plus has developed the online Environmental Help Desk with the Green Supply Chain Information tool. In developing the tool, we focused on the transportation and warehousing industry. Through our research and analysis, companies may use the Green Supply Chain Information tool to better guide their decisions by finding out the major issues in their field, what industry leaders are doing, the resources and certifications available, costs and benefits of certain practices, and the stages of sustainable progress for a company.Item Open Access Environmental Help Desk for Transportation and Warehousing Industries(2013-04-24) Xie, Yilin; Gelsinger, Taylor; Chou, Joseph; Yuan, YuanCompanies today face a variety of challenges and opportunities when considering investing in the environmental sustainability of their business. Compared to large companies, small and medium sized businesses do not have the resources available to leverage for consultants or invest in capital intensive projects. Therefore, Green Plus has developed the online Environmental Help Desk with the Green Supply Chain Information tool. In developing the tool, we focused on the transportation and warehousing industry. Through our research and analysis, companies may use the Green Supply Chain Information tool to better guide their decisions by finding out the major issues in their field, what industry leaders are doing, the resources and certifications available, costs and benefits of certain practices, and the stages of sustainable progress for a company.Item Open Access Environmental Help Desk for Transportation and Warehousing Industries(2013-04-24) Chou, Joseph; Gelsinger, Taylor; Yuan; Xie, YilinCompanies today face a variety of challenges and opportunities when considering investing in the environmental sustainability of their business. Compared to large companies, small and medium sized businesses do not have the resources available to leverage for consultants or invest in capital intensive projects. Therefore, Green Plus has developed the online Environmental Help Desk with the Green Supply Chain Information tool. In developing the tool, we focused on the transportation and warehousing industry. Through our research and analysis, companies may use the Green Supply Chain Information tool to better guide their decisions by finding out the major issues in their field, what industry leaders are doing, the resources and certifications available, costs and benefits of certain practices, and the stages of sustainable progress for a company.Item Open Access Environmental Help Desk For U.S. Transportation and Warehousing Industry(2013-04-24) Gelsinger, Taylor; Xie, Yilin; Chou, Joseph; Yuan, YuanCompanies today face a variety of challenges and opportunities when considering investing in the environmental sustainability of their business. Compared to large companies, small and medium sized businesses do not have the resources available to leverage for consultants or invest in capital intensive projects. Therefore, Green Plus has developed the online Environmental Help Desk with the Green Supply Chain Information tool. In developing the tool, we focused on the transportation and warehousing industry. Through our research and analysis, companies may use the Green Supply Chain Information tool to better guide their decisions by finding out the major issues in their field, what industry leaders are doing, the resources and certifications available, costs and benefits of certain practices, and the stages of sustainable progress for a company.Item Open Access Fractures, Faults, and Hydrothermal Systems of Puna, Hawaii, and Montserrat, Lesser Antilles(2010) Kenedi, Catherine LewisThe focus of this work is to use geologic and geophysical methods to better understand the faults and fracture systems at Puna, in southeastern Hawaii, and southern Montserrat, in the Lesser Antilles. The particular interest is understanding and locating the deep fracture networks that are necessary for fluid circulation in hydrothermal systems. The dissertation first presents a study in which identification of large scale faulting places Montserrat into a tectonic context. Then follow studies of Puna and Montserrat that focus on faults and fractures of the deep hydrothermal systems.
The first chapter consists of the results of the SEA-CALIPSO experiment seismic reflection data, recorded on a 48 channel streamer with the active source as a 2600 in3 airgun. This chapter discusses volcaniclastic debris fans off the east coast of Montserrat and faults off the west coast. The work places Montserrat in a transtensional environment (influenced by oblique subduction) as well as in a complex local stress regime. One conclusion is that the stress regime is inconsistent with the larger arc due to the influence of local magmatism and stress.
The second chapter is a seismic study of the Puna hydrothermal system (PHS) along the Kilauea Lower East Rift Zone. The PHS occurs at a left step in the rift, where a fracture network has been formed between fault segments. It is a productive geothermal field, extracting steam and reinjecting cooled, condensed fluids. A network of eight borehole seismometers recorded >6000 earthquakes. Most of the earthquakes are very small (< M.2), and shallow (1-3 km depth), likely the result of hydrothermal fluid reinjection. Deeper earthquakes occur along the rift as well as along the south-dipping fault plane that originates from the rift zone.
Seismic methods applied to the PHS data set, after the initial recording, picking, and locating earthquakes, include a tomographic inversion of the P-wave first arrival data. This model indicates a high seismic velocity under the field that is thought to be an intrusion and the heat source of the hydrothermal system. A shear wave splitting study suggested the PHS fracture system is largely oriented rift-parallel with some orthogonal fractures. Shear wave splitting data also were used in a tomographic inversion for fracture density. The fracture density is high in the PHS, which indicates high permeability and potential for extensive fluid circulation. This has been confirmed by high fluid flow and energy generation. The high fracture density is consistent with the interpretation of a transfer zone between the rift segments where a fracture mesh would be expected. In Puna the transfer zone is a relay ramp.
The results from the PHS are used as an example to examine the proposed hydrothermal system at St. George's Hill, Montserrat. In southern Montserrat, hot springs and fumaroles suggest a deep hydrothermal system heated by local magmatism. A magnetotelluric study obtained resistivity data that suggest focused alteration under southeastern Montserrat that is likely to be along fault segments. Several faults intersect under SGH, making it the probable center of the hydrothermal system. At Puna, and also Krafla, Iceland, where faults interact is an area of increased permeability, acting as a model to be applied to southern Montserrat. The conclusion is that in both Puna and Montserrat large faults interact to produce local areas of stress transfer that lead to fracturing and permeable networks; these networks allow for high-temperature hydrothermal circulation.
Item Open Access From Layered Intrusions to Mid-Ocean Ridges: The Petrography and Geochemistry of Basaltic Magmas(2020) Wernette, Benjamin WilsonThe geochemical evolution of basaltic magmas, in a variety of settings, has been the subject of countless studies. In some instances, basaltic magmas evolve to form economic transition and precious metal ore bodies. The metals extracted from these ore bodies are of critical importance to a wide variety of industries, such as automotive manufacturing. On a larger scale, basaltic magmas evolve to form the oceanic crust, the interface between the Earth’s mantle and the oceans. These are just two examples of how basaltic magmas are entwined with life on Earth and together represent the focus of this dissertation.
The second chapter of this dissertation uses detailed petrography to characterize the late-stage evolution of the Eocene Skaergaard Intrusion, Greenland. Significantly, this study identifies textural and chemical evidence that suggests that late hydrothermal fluids modified the Skaergaard transition (copper) and precious metal (silver, gold, platinum) budget.
The third chapter examines the major and trace element concentrations, as well as the 87Sr/86Sr ratios, for a suite of basaltic lavas dredged from the Cocos-Nazca Spreading Center, the Dietz Volcanic Ridge, and the East Pacific Rise. Prior to this study, this region of the Pacific basin was sparsely sampled. Notably, this study determines that lavas from the Cocos-Nazca Spreading Center are chemically depleted and are likely sourced from mantle that differs from that characteristic of normal mid-ocean ridge basalt.
Finally, the fourth chapter examines the size distribution, morphology, and chemical composition of plagioclase in plagioclase phyric lavas from the Cocos-Nazca Spreading Center. A variety of plagioclase morphologies, textures, and chemical compositions are reported. Importantly, this study demonstrates that combining size distribution analysis with textural and compositional information can provide nuanced information about the processes occurring beneath mid-ocean ridges.
Item Open Access Geochemistry of Dikes and Lavas from Tectonic Windows(2007-07-18) Pollock, MeagenTectonic windows are faulted escarpments that expose extensive sections of in situ oceanic crust, providing valuable opportunities to examine upper crustal architecture from a perspective unmatched by other approaches. Recent investigations of tectonic windows by submersible (Alvin, Nautile) and remotely-operated vehicle (Jason II) have recovered an unprecedented suite of dikes and lavas. We focus on compositions of dikes and lavas from intermediate- and super-fast rate crust exposed, respectively, in the Western Blanco Transform (BT) fault and the Pito Deep Rift (PD), to better understand accretionary processes at mid-ocean ridges. In the BT, the upper lavas are generally more primitive than the lower lavas, supporting geophysical and geological studies that suggest off-axis volcanism plays an important role in constructing the upper crust at intermediate-rate spreading centers. The wide range in lava compositions exposed along the BT scarp also lends caution to studies that rely on surface lavas to determine the evolution of sub-axial magmatic conditions.The PD suite allows us to examine accretionary processes over an impressive temporal range, including long-term (millions of years) changes in mantle composition and medium-rate (100s of ka) changes in magmatic regime. Compositions of adjacent dikes reveal that the ocean crust is heterogeneous on short time (<10>ka) and spatial (meters) scales, reflecting along-axis transport of magma from chemically heterogeneous portions of the melt lens. High compositional variability was also observed in adjacent dikes from Hess Deep (HD), a tectonic window into fast-rate crust, suggesting that lateral dike intrusion occurs at all mid-ocean ridges. PD lavas are offset to lower density compositions compared to dikes, an observation previously made in HD, but made here for the first time in other dike-lava populations, suggesting that buoyancy plays a major role in partitioning magma between dikes and lavas. A model for intrusion of a single dike shows that crustal density, magma pressure, and tectonic stress affect the intensity of density-based magma partitioning in a systematic way that can be related to compositions of dike-lava populations.Item Open Access Global Biogeochemical Cycle of Lithium(Global Biogeochemical Cycles) Schlesinger, William H; Klein, Emily M; Wang, Zhen; Vengosh, AvnerItem Open Access Global biogeochemical cycle of vanadium.(Proc Natl Acad Sci U S A, 2017-12-11) Schlesinger, William H; Klein, Emily M; Vengosh, AvnerSynthesizing published data, we provide a quantitative summary of the global biogeochemical cycle of vanadium (V), including both human-derived and natural fluxes. Through mining of V ores (130 × 109 g V/y) and extraction and combustion of fossil fuels (600 × 109 g V/y), humans are the predominant force in the geochemical cycle of V at Earth's surface. Human emissions of V to the atmosphere are now likely to exceed background emissions by as much as a factor of 1.7, and, presumably, we have altered the deposition of V from the atmosphere by a similar amount. Excessive V in air and water has potential, but poorly documented, consequences for human health. Much of the atmospheric flux probably derives from emissions from the combustion of fossil fuels, but the magnitude of this flux depends on the type of fuel, with relatively low emissions from coal and higher contributions from heavy crude oils, tar sands bitumen, and petroleum coke. Increasing interest in petroleum derived from unconventional deposits is likely to lead to greater emissions of V to the atmosphere in the near future. Our analysis further suggests that the flux of V in rivers has been incremented by about 15% from human activities. Overall, the budget of dissolved V in the oceans is remarkably well balanced-with about 40 × 109 g V/y to 50 × 109 g V/y inputs and outputs, and a mean residence time for dissolved V in seawater of about 130,000 y with respect to inputs from rivers.Item Open Access Global correlations of ocean ridge basalt chemistry with axial depth and crustal thickness.(Journal of Geophysical Research, 1987-12-01) Klein, Emily M; Langmuir, CHThermal modeling independently predicts the observed relationships among basalt chemistry, ridge depth, and crustal thickness resulting from temperature variations in the mantle. Beneath the shallowest and deepest ridge axes, temperature differences of approximately 250oC in the subsolidus mantle are required to account for the global systematics. -from AuthorsItem Open Access Local versus global variations in ocean ridge basalt composition: A reply(Journal of Geophysical Research: Solid Earth, 1989) Klein, Emily M; Langmuir, Charles HItem Open Access Plastic Reduction Case Studies(2015-04-24) Su, Shengyuan; Li, Yazhou; Maschal, Emma; Ha, YuejiaoPlastic is one of the most commonly-used and convenient materials in most societies around the world. The use of plastic is increasingly controversial, however, due to its negative impacts on the environment, biodiversity, and human health. Two particularly plastic-intensive industries, hotels and restaurants, have initiated efforts to reduce, recycle, and reuse plastic in their operations. This project aims to investigate current plastic reduction practices in the restaurant and hotel industries, and to provide practical strategy suggestions for the improvement of sustainability performance in these and related business sectors. Focusing on the practices of five partner restaurants and five partner hotels, we collected information through phone interviews, an online survey, and online research. This revealed each company’s basic operation, plastic usage, plastic reduction initiatives, and motivations to promote plastic sustainability. We found that although the sample companies have adopted initiatives to reduce plastic and have achieved some success, all of them encounter significant challenges. In addition, there are differences between the hotel and restaurant sectors, as well as among different companies within each sector, in terms of the scales, types, and motivations for plastic reduction. Synthesizing the information we collected, we provide several practical strategies and recommendations for the restaurant and hotel industries to develop plastic reduction practices, and to communicate their initiatives, progress, and performance to the public. For example, we advise that restaurants and hotels cooperate with non-governmental organizations, government programs, and high-tech companies to gain additional support for their plastic pollution reduction initiatives. In addition, it might be an effective strategy to provide financial incentives to change consumers’ behavior of plastic usage. Other suggested strategies include material replacement, recycling and reuse, educating staff to improve the employee engagement, and cooperating with responsible suppliers. This initial study can be expanded in the future to include more sample companies in these two industries, as well as other plastic-intensive industries, such as airline companies and supermarket stores.Item Open Access Seafloor photo-geology and sonar terrain modeling at the 9°N overlapping spreading center, East Pacific Rise(Geochemistry, Geophysics, Geosystems, 2013-12-01) Klein, Emily M; White, Scott M; Nunnery, James Andrew; Mason-Stack, Jessica L; Wanless, V Dorsey; Perfit, Michael R; Waters, Christopher L; Sims, Kenneth WW; Fornari, Daniel J; Zaino, Anne J; Ridley, W IanA fundamental goal in the study of mid-ocean ridges is to understand the relationship between the distribution of melt at depth and seafloor features. Building on geophysical information on subsurface melt at the 9°N overlapping spreading center on the East Pacific Rise, we use terrain modeling (DSL-120A side scan and bathymetry), photo-geology (Jason II and WHOI TowCam), and geochemical data to explore this relationship. Terrain modeling identified four distinct geomorphic provinces with common seafloor characteristics that correspond well to changes in subsurface melt distribution. Visual observations were used to interpret terrain modeling results and to establish a relative seafloor age scale, calibrated with radiometric age dates, to identify areas of recent volcanism. On the east limb, recent eruptions in the north are localized over the margins of the 4 km wide asymmetric melt sill, forming a prominent off-axis pillow ridge. Along the southern east limb, recent eruptions occur along a neovolcanic ridge that hugs the overlap basin and lies several kilometers west of the plunging melt sill. Our results suggest that long-term southward migration of the east limb occurs through a series of diking events with a net southward propagation direction. Examining sites of recent eruptions in the context of geophysical data on melt distribution in the crust and upper mantle suggests melt may follow complex paths from depth to the surface. Overall, our findings emphasize the value of integrating information obtained from photo-geology, terrain modeling, lava geochemistry and petrography, and geophysics to constrain the nature of melt delivery at mid-ocean ridges. Key Points Terrain modeling and photogeology show links between eruptions and crustal melt Eruptions above 4-km wide melt sill occur only above sill's margins Terrain modeling found four provinces that differ from classic tectonic view of OSC © 2013 The Authors. Geochemistry, Geophysics, Geosystems published by Wiley Periodicals, Inc. on behalf of American Geophysical Union.