Browsing by Subject "Alkadienes"
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Item Open Access Platinum(II)-catalyzed intermolecular hydroamination of monosubstituted allenes with secondary alkylamines.(Chem Commun (Camb), 2010-03-14) Toups, Kristina L; Widenhoefer, Ross AA 1:1 mixture of (dppf)PtCl(2) and AgOTf (5 mol%) catalyzed the intermolecular hydroamination of monosubstituted allenes with secondary alkylamines at 80 degrees C to form allylic amines in good yield with selective formation of the E-diastereomer.