Browsing by Subject "Water"
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Item Open Access A broad survey of hydraulic and mechanical safety in the xylem of conifers.(Journal of experimental botany, 2014-08) Bouche, Pauline S; Larter, Maximilien; Domec, Jean-Christophe; Burlett, Régis; Gasson, Peter; Jansen, Steven; Delzon, SylvainDrought-induced forest dieback has been widely reported over the last decades, and the evidence for a direct causal link between survival and hydraulic failure (xylem cavitation) is now well known. Because vulnerability to cavitation is intimately linked to the anatomy of the xylem, the main objective of this study was to better understand the xylem anatomical properties associated with cavitation resistance. An extensive data set of cavitation resistance traits and xylem anatomical properties was developed for 115 conifer species, with special attention given to the micro-morphology of bordered pits. The ratio of torus to pit aperture diameter, so-called torus overlap, increased with increasing cavitation resistance, while the flexibility of the margo does not seem to play a role, suggesting that air-seeding is located at the seal between the aspirated torus and pit aperture. Moreover, punctured tori were reported in various Pinaceae species. Species resistant to cavitation had thicker tracheid walls, while their lumen diameter (conduit size) was only slightly reduced, minimizing the impact on hydraulic conductance. The results also demonstrated (i) the existence of an indirect trade-off between hydraulic safety and mechanical strength; and (ii) a consistency between species distribution and xylem anatomy: species with a wide torus overlap and high valve effects are found in arid environments such as the Mediterranean region.Item Open Access A Sustainability Plan for American Tobacco Campus(2011-04-29) Lareau, Courtney; Rankin, Kimberlee; Tucker, BunnyAmerican Tobacco Campus (ATC) Management has committed to understanding the environmental impact of their campus and making strategic improvements, while reducing operational costs. This Masters Project focused on determining ATC’s environmental impacts by collecting baseline data on the three key impact areas designated by ATC Management: energy use, water consumption, and waste generation. Initial reduction goals were then established and strategies were developed to achieve reductions that would help ATC Management make progress toward achieving these goals. Tenant and employee engagement were additional factors considered in strategic initiatives. This Sustainability Plan for American Tobacco Campus represents an initial assessment of ATC’s environmental performance.Item Open Access An Assessment of Sustainable Water Management at University Campuses(2011) McHugh, Amani NSustainable water management is needed to ensure quality supplies of our vital water resources in the face of growing human demand for water, high levels of pollution, and increasing spatial and temporal variability associated with climate change. An integrated approach to water management is recommended to address current water challenges, which are often interrelated with other environmental, economic and social issues. Universities and colleges have missions, resources, and contexts that could enable them to lead the process of developing and applying sustainable and integrated water resource management (IWRM). The opportunity to exemplify integrated water management has grown as institutions of higher education have made progress towards incorporating environmental sustainability into teaching, research, and campus operations. This dissertation examines the issue of campus water management at institutions of higher education through a review of campus sustainability literature, a survey of sustainability and facilities managers, and case studies of three campus water-related projects.
Findings from the review of campus sustainability literature and websites suggests water is less of a campus management priority than issues such as energy and climate change; furthermore, where water is addressed, the focus is on water conservation, while water quality management is overlooked. IWRM is not explicitly discussed in the campus sustainability literature reviewed, though principles relevant to IWRM are included in some campus sustainability declarations and programs. Results from the survey substantiate the findings from literature review that water management is less of an institutional priority than energy management and water quality management is often underemphasized in campus management. According to the survey respondents, campus water management at the institutions represented was on average just adequately managed and institutions were minimally prepared to deal with several types of future water problems. Facilities managers tended to rate their institution's water management as slightly more effective compared to sustainability coordinators. Many campuses relied on top-down, engineering based water management approaches, rather than integrated and interdisciplinary water management. Individual initiatives, municipal codes and policies, campus community sustainability awareness, and campus environmental projects served as drivers for more sustainable water management, while budget constrains were a common barrier. Logistic regression analysis of the survey data revealed that institutions featuring stream and wetland restoration projects had greater odds of being described as having a developed watershed plan and taking into consideration multidisciplinary approaches to water management.
Case studies showed that wetland creation and restoration projects can serve as effective teaching and research laboratories for institutions of higher education, but that none of the studied cases fully exemplified IWRM in their operation. Of the three cases studied, the Stream and Wetland Assessment Management Park project at Duke University most closely demonstrated a campus project designed and developed to address water problems in the campus watershed, while also offering an effective outdoor teaching and research laboratory for hundreds of students, professionals, and researchers. The Olentangy River Wetland Research Park case at Ohio State University exemplified the potential for wetland creation and restoration projects to serve as a facility for educating thousands of students and visitors, training dozens of water experts, and influencing wetland and water resource management beyond the campus. The Radford University Stormwater Treatment Wetland Project case illustrated the potential for institutions with limited space and resources to establish effective outdoor teaching laboratories using environmental features already present or in development on campus.
Findings from the review, survey and case studies all point toward the need and opportunity for institutions of higher education to make greater efforts at implementing and promoting sustainable and integrated water resource management. Literature review and survey findings reveal that water is frequently overlooked as environmental resource at universities and colleges, while other environmental issues such as energy, climate change and recycling are prioritized in sustainability plans and efforts. Universities and colleges have made progress addressing water conservation, while water quality and stormwater need further attention and an integrated approach for more effective management.
Item Open Access An Examination of PFAS for North Carolina Policymakers and Researchers(2021-04-30) Kluck, Johanna; Nocera, Karly; Zhang, QixuanThis Master’s Project aims to explore factors impacting the occurrence, distribution, toxicology and remediation of PFAS – a type of emerging contaminant – in North Carolina’s water. Research methods utilized include a literature review, interviews, and quantitative data analysis of Department of Environmental Quality’s water quality samples. Due to a lack of publicly available information and regulatory oversight, many PFAS-related concerns – such as identifying individual households at risk – are unable to be effectively addressed in the scope of this project. The team sought to synthesize existing knowledge and identify gaps in order to inform both the academic community’s future research and upcoming policy efforts. To better connect and communicate ongoing research with non-academic communities, as well as identify areas of PFAS knowledge that need further investigation, our final product involves multiple deliverables: (1) a scientific paper with an extensive literature review, and (2) an ESRI StoryMap conveying our findings and synthesis in a publicly accessible format and language.Item Open Access Analyzing the Connections Among Water Access, Sanitation, Malaria and Diarrhea Outcomes in Rural Central Uganda(2016-04-22) Hu, MichaelAccess to safe water and sanitation around the world has increased significantly in the past few decades. The United Nations claims that 91% of the world’s population has access to safe water, exceeding the Millennium Development Goal for water access. Yet, some evidence in the literature suggests that safe water and sanitation access is overestimated, as the common indicator used to estimate safe water is infrastructural. The usage of water, behaviors surrounding water acquisition and storage, and possible contamination along the source to point-of-use continuum is poorly understood. This cross-sectional epidemiological study used a combination of surveying, mapping and bacteriological water testing to identify some of the possible factors in water contamination, and relationships with malaria and diarrhea burden, in a parish in Central Uganda. Secondary goals included assessing the burden of malaria and diarrhea in the parish, and assessing the use of mapping and water testing as field research tools. The survey included questions on water acquisition and usage behavior, sanitary conditions, knowledge of diarrhea, and malaria and diarrhea burden. In this parish, 126 households across 9 villages were randomly chosen to be surveyed, mapped and water tested. All water sources in the parish were additionally mapped and water tested. Across all water sources, including piped water, the water quality at the household point-of-use level was drastically worse than quality measured at the source. In fact, among all water sources, piped water recipients showed the highest average bacterial loads, despite the clean quality of the source itself. Possible factors in lowering or raising contamination, as displayed by regression results, include the frequency of obtaining water and distance from the water source respectively. The malaria and diarrhea case sample size proved smaller than expected, and challenges remain in using mapping and water testing in the field. These results support the theories that the amount of people with access to safe water is overestimated, and that contamination exists along the source to point-of-use continuum. More research is needed to investigate the exact points of contamination in the spectrum and possible contaminating factors.Item Open Access Analyzing the Feasibility of a Centralized Treatment System for the Implementation of Destructive PFAS Treatment Technology(2023-04-26) Carpenter, Jack; Guimond, Austin; O'Callaghan, Ariel; von Turkovich, NataliePer- and polyfluoroalkyl substances (PFAS), are emerging contaminants that pose a significant threat to water systems across the U.S. PFAS compounds are difficult to break down and long-term exposure to them can have adverse health effects. 374Water is a technology company that has developed a destructive solution for organic wastes including PFAS through a process called supercritical oxidation. This study examined the financial feasibility of implementing their technology in a centralized wastewater treatment system. It assessed whether the centralized model is viable for 374Water and for individual utilities in North Carolina and Maine. Study results showed a positive business case for Maine. In North Carolina, where there is limited PFAS policy, project implementation was not feasible. 374Water AirSCWO™ implementation should be focused on states with strict PFAS disposal regulations that drive up biosolid disposal costs.Item Open Access Assessing Community Based Water Organization Performance in Central America(2017-06-26) Browning, NeilWhat are the effects of household, community, technical, and environmental variables on the performance and resilience of CWOs in dry regions? Since 2014, drought has severely affected Central American economic and health outcomes, necessitating international intervention. 2.5 million people were at risk of food insecurity across the region in 2014, and 65% of homes had no stock of food during the 2015 harvest season. Low-income families living in Central America’s “dry corridor” are affected the most by droughts; the UN’s long-term plan is to build climate resilience in these communities as climate change increases the magnitude and frequency of droughts. Local community-based drinking water organizations (CWOs) are key actors in Central American water provision. In rural and urban peripheral areas, CWOs provide the populace with up to 60% of its drinkable water. As climate change strains water accessibility, these local institutions will require effective management strategies so they have the capacity to handle the resource declines they will experience. I assessed how different independent variables are associated with the adaptive capacity of CWOs and identified attributes that lead to success by conducting regression analyses on a data set from three Central American countries: Costa Rica, Guatemala, and Nicaragua. I also compared the statistically significant outcomes across the three countries. The regressions are based on survey data that has been gathered at the household and CWO level, technical data that was collected by engineers, as well as environmental and census data on the subnational regions in question. First, I examined household reports of water access – defined as number of hours per day. I analyzed how this definition of water access related to household, engineering, community-level, and environmental variables. I found that volumetric pricing and elevation are the key variables to consider when designing an effective governance structure for a Central American CWO. I also determined that it is possible that national norms in CWO procedures may overstate the effect of volumetric pricing. Second, I used three different engineering variables as dependent and analyzed how they were affected by household, community-level and environmental variables. Unlike the hours of service variable, the engineering variables were collected at the community level by engineers, rather than self-reported at the household level. I conclude that elevation and volumetric pricing are the most relevant variables to consider in effective rural water provision. Elevation increases the start-up and maintenance costs of obtaining water. Volumetric pricing should be promoted as well, as it encourages the regulation of scarce water resources in the simplest way. I also conclude that higher elevation communities require more maintenance from community members, and require more expensive and powerful pumping technology.Item Open Access Assessing the nonlinear association of environmental factors with antibiotic resistance genes (ARGs) in the Yangtze River Mouth, China.(Scientific reports, 2023-11) Miao, Jiazheng; Ling, Yikai; Chen, Xiaoyuan; Wu, Siyuan; Liu, Xinyue; Xu, Shixin; Umar, Sajid; Anderson, Benjamin DThe emergence of antibacterial resistance (ABR) is an urgent and complex public health challenge worldwide. Antibiotic resistant genes (ARGs) are considered as a new pollutant by the WHO because of their wide distribution and emerging prevalence. The role of environmental factors in developing ARGs in bacterial populations is still poorly understood. Therefore, the relationship between environmental factors and bacteria should be explored to combat ABR and propose more tailored solutions in a specific region. Here, we collected and analyzed surface water samples from Yangtze Delta, China during 2021, and assessed the nonlinear association of environmental factors with ARGs through a sigmoid model. A high abundance of ARGs was detected. Amoxicillin, phosphorus (P), chromium (Cr), manganese (Mn), calcium (Ca), and strontium (Sr) were found to be strongly associated with ARGs and identified as potential key contributors to ARG detection. Our findings suggest that the suppression of ARGs may be achieved by decreasing the concentration of phosphorus in surface water. Additionally, Group 2A light metals (e.g., magnesium and calcium) may be candidates for the development of eco-friendly reagents for controlling antibiotic resistance in the future.Item Open Access Assessing the Water Footprint of Electric Car Batteries – A Dive into the Water-Energy Nexus(2023-04-28) MacDonald, Kathlyn; Thornton, Karen; Allen, Mary Margaret; Katayama, TaroWater has been historically overlooked as a criterion when measuring the environmental impact of a project. This project aims to visualize the water impacts and risks associated with extracting three critical minerals commonly used in electric vehicle (EV) batteries (lithium, cobalt, and nickel) on behalf of Rivian – an EV manufacturing company. As EVs become increasingly popular, the demand for minerals and metals used in their production, such as lithium, cobalt, and nickel, has increased. The mining of these minerals often takes place in water-stressed areas, which can have negative environmental and social impacts. The goal of this project is to assess the water risks associated with mining these minerals and provide recommendations for a more sustainable supply chain. The objectives of this project are to identify potential "hot spots" in the EV supply chain where water risks are most prevalent, evaluate the consumption of water from mining the three minerals, and provide recommendations to create a more sustainable supply chain. We narrowed the supply chain to include an analysis of the mining of three critical EV battery raw materials – lithium, cobalt, and nickel. We researched the specific supply chains of these three minerals and found the geographic location of the top 10 mines by production, with some exceptions. These mines were then overlayed with water scarcity data from WRI’s Aqueduct tool. A dashboard was created to express these findings. In the interest of transparency, we made sure to gather as much water consumption data as possible for the mining processes of lithium, cobalt, and nickel. Though we encountered some limitations during this process, such as differing functional units and definitions of water consumption/use, we did our best to create an informative table displaying our findings. We acknowledge that some of our sources lacked scientific confidence and our sample may not have been fully representative. Potential supply chain hot spots - mines located in areas of high stress extremely high stress, or arid and low water use - were located for each mineral. For cobalt, the potential hot spots included the Murrin Murrin mine in Australia. For lithium, the potential hot spots include Sociedad Quimica y Minera de Chile and Albemarle’s Chile operations. It is also important to note the Greenbush Mine in Australia was located less than 10 miles from a location of high water scarcity and thus, was included in our potential hot spots. For nickel, the potential hot spots include Mount Keith Mine in Australia. The broader ramifications of this work include the potential to promote more sustainable practices within the EV industry. By identifying potential "hot spots" in the supply chain where water stress risks are most present, this project provides a framework for developing a more sustainable supply chain. The recommendations provided in this project can help stakeholders in the EV industry to make more wholistic decisions about the environmental and social impacts of their production practices by including water consumption impacts. This project highlights the need for greater attention to be paid to water scarcity within the EV supply chain. By analyzing the water risks associated with mining critical minerals for EVs and providing recommendations for a more sustainable supply chain, this project seeks to promote more responsible production practices within the EV industry. The findings of this project have the potential to inform future research and policy initiatives aimed at addressing the environmental and social impacts of EV production. Moving forward, there is a need for more comprehensive data on water consumption and direct engagement with upstream suppliers to better understand the potential risks at these locations. Companies in the EV industry should also assess the sustainability of their supply chains on an individual level and explore alternative sources for critical minerals to reduce reliance on high-risk locations.Item Open Access Bacterial pathogens deliver water- and solute-permeable channels to plant cells.(Nature, 2023-09) Nomura, Kinya; Andreazza, Felipe; Cheng, Jie; Dong, Ke; Zhou, Pei; He, Sheng YangMany animal- and plant-pathogenic bacteria use a type III secretion system to deliver effector proteins into host cells1,2. Elucidation of how these effector proteins function in host cells is critical for understanding infectious diseases in animals and plants3-5. The widely conserved AvrE-family effectors, including DspE in Erwinia amylovora and AvrE in Pseudomonas syringae, have a central role in the pathogenesis of diverse phytopathogenic bacteria6. These conserved effectors are involved in the induction of 'water soaking' and host cell death that are conducive to bacterial multiplication in infected tissues. However, the exact biochemical functions of AvrE-family effectors have been recalcitrant to mechanistic understanding for three decades. Here we show that AvrE-family effectors fold into a β-barrel structure that resembles bacterial porins. Expression of AvrE and DspE in Xenopus oocytes results in inward and outward currents, permeability to water and osmolarity-dependent oocyte swelling and bursting. Liposome reconstitution confirmed that the DspE channel alone is sufficient to allow the passage of small molecules such as fluorescein dye. Targeted screening of chemical blockers based on the predicted pore size (15-20 Å) of the DspE channel identified polyamidoamine dendrimers as inhibitors of the DspE/AvrE channels. Notably, polyamidoamines broadly inhibit AvrE and DspE virulence activities in Xenopus oocytes and during E. amylovora and P. syringae infections. Thus, we have unravelled the biochemical function of a centrally important family of bacterial effectors with broad conceptual and practical implications in the study of bacterial pathogenesis.Item Open Access Collaborative Water Risk Management: Guidelines for the Power Industry, Water Utility, and Regulator(2011-04-28) Shpitsberg, AnnaSafe and adequate access to energy and water, the two natural resources driving the production of all other critical human needs, is key to economic development, public health, and military security. The availability of these two resources is threatened by the increase in demand and competing interests for their supply. Water resources are critical to energy production while energy resources are necessary for safe deployment and allocation of water. The constraints imposed by such reliance are evident in the thermoelectric and water supply industries, which must procure water to ensure operation while complying with water quantity and quality regulations. Thermoelectric plants are responsible for almost 90% of the generation capacity and 41% of the freshwater withdrawals in the United States (Kenny, et al. 2009). Water suppliers are responsible for 13% of freshwater withdrawals while 75% of a municipalities cost to process and distribute water is spent on electricity (Sandia National Laboratory 2006). This study discusses the current framework and pricing structure under which a power and water utility operate and focuses on the relationship between these utilities, in order to identify collaborative strategies that ease dependence on both resources. The research identifies the main roadblocks to effective management including impeded flow of information, inaccurate pricing models, and increasing stress to water resources. To address the aforementioned roadblocks, five recommendations are presented with case studies serving as reference points. This guideline proposes the implementation of accurate price signals, demand response measures, collaborative efficiency programs, alternative water sources, and alternative energy sources to ease water constraints. Recommendations are the result of extensive literature and data review, as well as interviews conducted with utilities, agencies, laboratories, research centers, and technology providers.Item Open Access Community Flood Assessment for Bucksport, South Carolina(2022-04-22) McLaughlin, Aislinn; Earnhardt, Rachel; Swit, Nadia; Murphy, RebeccaBucksport, South Carolina has experienced recurring high-impact flood events in the past decade that threaten local property, public health, and cultural heritage. This report aims to support the resilience of the community through a science and policy-based assessment of the factors contributing to flooding in the region. Findings from our hydrologic analyses indicate that a greater frequency of high magnitude precipitation events coupled with slower watershed drainage have led to longer standing water in the community after storm events. Results also reflect that these impacts will likely be exacerbated by climate change-attributed precipitation increases over the next century. Accordingly, our exploration of the relevant flood policy landscape highlights recommendations for the community to adapt and mitigate future flooding impacts through both state and federal-level funding for watershed-scale planning and resilience-focused investment.Item Open Access Comparisons of Carbon and Water Fluxes of Pine Forests in Boreal and Temperate Climatic Zones(2015) Torngern, PantanaQuantifying carbon fluxes and pools of forest ecosystems is an active research area in global climate study, particularly in the currently and projected increasing atmospheric carbon dioxide concentration environment. Forest carbon dynamics are closely linked to the water cycle through plant stomata which are regulated by environmental conditions associated with atmospheric and soil humidity, air temperature and light. Thus, it is imperative to study both carbon and water fluxes of a forest ecosystem to be able to assess the impact of environmental changes, including those resulting from climate change, on global carbon and hydrologic cycles. However, challenges hampering such global study lie in the spatial heterogeneity of and the temporal variability of fluxes in forests around the globe. Moreover, continuous, long-term monitoring and measurements of fluxes are not feasible at global forest scale. Therefore, the need to quantify carbon and water fluxes and to identify key variables controlling them at multiple stands and time scales is growing. Such analyses will benefit the upscaling of stand-level observations to large- or global-scale modelling approaches.
I performed a series of studies investigating carbon and water fluxes in pine forests of various site characteristics, conditions and latitudinal locations. The common techniques used in these studies largely involved sap flux sensors to measure tree-level water flow which is scaled up to stand-level transpiration and a process-based model which calculates canopy light absorption and carbon assimilation constrained by the sap-flux beased canopy stomatal conductance (called Canopy Conductance Constrained Carbon Assimilation or 4C-A model). I collected and analyzed sap flux data from pine forests of two major species: Pinus taeda in temperate (36 °N) and Pinus sylvestris in boreal (64 °N) climatic zones. These forests were of different stage-related canopy leaf area and some were under treatments for elevated atmospheric CO2 concentration or fertilization.
I found that (Chapter 2) the 17-year long free-air CO2 enrichment (FACE) had little effect on canopy transpiration of a mixed forest with the dominant P. taeda and other broadleaved species as the understory in North Carolina, USA (Duke FACE). The result was due to the compensation of elevated [CO2]-induced increase of canopy leaf area for the reduction of mean canopy stomatal conductance. My next theoretical study (Chapter 3), comparing P. taeda (native at 36 °N in North Carolina), P. sylvestris (native at 64 °N in norther Sweden) and Pinus contorta (native at 58 °N in British Columbia, Canada) canopies, revealed that the interaction between crown architecture and solar elevation associated with site latitude of pine canopies affected the distribution and total amount of canopy light absorption and potentially photosynthesis such that the latitudinally prescribed needle organization of a pine canopy is optimal for light interception and survival in its native location. Then, I quantified and analyzed water fluxes in four pine forests: one composed of P. taeda in North Carolina and three containing P. sylvestris in northern Sweden (Chapter 4). The latter forests consisted of various stage-related canopy leaf area and nutrient status. Combining my estimates with other published results from forests of various types and latitudinal locations, I derived an approach to estimate daily canopy transpiration during the growing season based on a few environmental variables including atmospheric and soil humidity and canopy leaf area. Moreover, based on a water budget analysis, I discovered that the intra-annual variation of precipitation in a forest has a small effect on evapotranspiration and primarily affecting outflow; however, variation of precipitation across latitudes proportionally influences anuual evapotranspiration and outflow. Furthermore, the hydrologic analyses implied the `disequilibrium' of forest water cycling during the growing season when forests may use less and more water in dry and wet regions, respectively, than the incoming precipitation. Nevertherless, at annual timescale, most forests became in `equilibrium' by using similar proportion of incoming precipitation. Finally, (Chapter 5) I estimated and analyzed the temporal and spatial variabilities of carbon fluxes of the same four forests measured in Chapter 4 using the 4C-A computational approach and analyzed their resource-use efficiencies. I concluded that, based on my results and others as available, despite the differences in species clumping and latitudes which influence growing season length and solar elevation, the gross primary productivity can be conservatively linearly related to the canopy light absorption. However, based on previous findings from a global study, different allocation of the acquired carbon to the above- and belowground is regulated by soil nutrient status.
Overall, the findings in this dissertation offer new insights into the impacts of environmental changes on carbon and water dynamics in forests across multiple sites and temporal scales which will be useful for larger-scale analyses such as those pertaining to global climate projection.
Item Open Access Control of the orientational order and nonlinear optical response of the "push-pull" chromophore RuPZn via specific incorporation into densely packed monolayer ensembles of an amphiphilic four-helix bundle peptide: characterization of the peptide-chromophore complexes.(J Am Chem Soc, 2010-08-18) Krishnan, Venkata; Tronin, Andrey; Strzalka, Joseph; Fry, H Christopher; Therien, Michael J; Blasie, J Kent"Push-pull" chromophores based on extended pi-electron systems have been designed to exhibit exceptionally large molecular hyperpolarizabilities. We have engineered an amphiphilic four-helix bundle peptide to vectorially incorporate such hyperpolarizable chromophores having a metalloporphyrin moiety, with high specificity into the interior core of the bundle. The amphiphilic exterior of the bundle facilitates the formation of densely packed monolayer ensembles of the vectorially oriented peptide-chromophore complexes at the liquid-gas interface. Chemical specificity designed into the ends of the bundle facilitates the subsequent covalent attachment of these monolayer ensembles onto the surface of an inorganic substrate. In this article, we describe the structural characterization of these monolayer ensembles at each stage of their fabrication for one such peptide-chromophore complex designated as AP0-RuPZn. In the accompanying article, we describe the characterization of their macroscopic nonlinear optical properties.Item Open Access Desalination and transboundary water governance in conflict settings.(Journal of environmental management, 2024-03) Walschot, Maureen; Katz, DavidDesalination can reduce both water scarcity and variability in supplies, two factors identified as drivers of transboundary water conflict. As such, some have predicted that increasing development of desalination capacity may reduce conflict over shared waters. Others have claimed that desalination may become a source of new conflicts. Additionally, desalination may open up new avenues for cooperation, but also may allow for unilateral action by parties, thereby decreasing cooperation. This study looks at the impact of the introduction of desalination on hydro-political relations in two protracted conflict settings: the island of Cyprus and the Arab-Israeli conflict. Using both quantitative and qualitative assessments, we find that desalination has fundamentally altered hydro-political relations, but find no consistent trends in terms of levels of conflict and cooperation. These findings suggest that the influence of desalination on hydro-political relations is likely to be a function of, rather than a transformer of, the larger geopolitical context.Item Open Access Differential coordination demands in Fe versus Mn water-soluble cationic metalloporphyrins translate into remarkably different aqueous redox chemistry and biology.(Inorganic chemistry, 2013-05-06) Tovmasyan, Artak; Weitner, Tin; Sheng, Huaxin; Lu, MiaoMiao; Rajic, Zrinka; Warner, David S; Spasojevic, Ivan; Reboucas, Julio S; Benov, Ludmil; Batinic-Haberle, InesThe different biological behavior of cationic Fe and Mn pyridylporphyrins in Escherichia coli and mouse studies prompted us to revisit and compare their chemistry. For that purpose, the series of ortho and meta isomers of Fe(III) meso-tetrakis-N-alkylpyridylporphyrins, alkyl being methyl to n-octyl, were synthesized and characterized by elemental analysis, UV/vis spectroscopy, mass spectrometry, lipophilicity, protonation equilibria of axial waters, metal-centered reduction potential, E(1/2) for M(III)P/M(II)P redox couple (M = Fe, Mn, P = porphyrin), kcat for the catalysis of O2(•-) dismutation, stability toward peroxide-driven porphyrin oxidative degradation (produced in the catalysis of ascorbate oxidation by MP), ability to affect growth of SOD-deficient E. coli, and toxicity to mice. Electron-deficiency of the metal site is modulated by the porphyrin ligand, which renders Fe(III) porphyrins ≥5 orders of magnitude more acidic than the analogous Mn(III) porphyrins, as revealed by the pKa1 of axially coordinated waters. The 5 log units difference in the acidity between the Mn and Fe sites in porphyrin translates into the predominance of tetracationic (OH)(H2O)FeP complexes relative to pentacationic (H2O)2MnP species at pH ∼7.8. This is additionally evidenced in large differences in the E(1/2) values of M(III)P/M(II)P redox couples. The presence of hydroxo ligand labilizes trans-axial water which results in higher reactivity of Fe relative to Mn center. The differences in the catalysis of O2(•-) dismutation (log kcat) between Fe and Mn porphyrins is modest, 2.5-5-fold, due to predominantly outer-sphere, with partial inner-sphere character of two reaction steps. However, the rate constant for the inner-sphere H2O2-based porphyrin oxidative degradation is 18-fold larger for (OH)(H2O)FeP than for (H2O)2MnP. The in vivo consequences of the differences between the Fe and Mn porphyrins were best demonstrated in SOD-deficient E. coli growth. On the basis of fairly similar log kcat(O2(•-)) values, a very similar effect on the growth of SOD-deficient E. coli was anticipated by both metalloporphyrins. Yet, while (H2O)2MnTE-2-PyP(5+) was fully efficacious at ≥20 μM, the Fe analogue (OH)(H2O)FeTE-2-PyP(4+) supported SOD-deficient E. coli growth at as much as 200-fold lower doses in the range of 0.1-1 μM. Moreover the pattern of SOD-deficient E. coli growth was different with Mn and Fe porphyrins. Such results suggested a different mode of action of these metalloporphyrins. Further exploration demonstrated that (1) 0.1 μM (OH)(H2O)FeTE-2-PyP(4+) provided similar growth stimulation as the 0.1 μM Fe salt, while the 20 μM Mn salt provides no protection to E. coli; and (2) 1 μM Fe porphyrin is fully degraded by 12 h in E. coli cytosol and growth medium, while Mn porphyrin is not. Stimulation of the aerobic growth of SOD-deficient E. coli by the Fe porphyrin is therefore due to iron acquisition. Our data suggest that in vivo, redox-driven degradation of Fe porphyrins resulting in Fe release plays a major role in their biological action. Possibly, iron reconstitutes enzymes bearing [4Fe-4S] clusters as active sites. Under the same experimental conditions, (OH)(H2O)FePs do not cause mouse arterial hypotension, whereas (H2O)2MnPs do, which greatly limits the application of Mn porphyrins in vivo.Item Open Access Ecological Limitations and Potentials of Artificial Aquatic Systems(2018) Clifford, ChelseaAn abstract of a dissertation: As humans increasingly alter the surface geomorphology of the Earth, a multitude of artificial aquatic systems have appeared, both deliberately and accidentally. Human modifications to the hydroscape range from alteration of existing waterbodies to construction of new ones. The extent and ecosystem services of these systems are underexplored, but likely substantial and changing. Instead of simply accepting that artificial ecosystems have intrinsically low values, environmental scientists should determine what combination of factors, including setting, planning and construction, subsequent management and policy, and time, impact the condition of these systems. Scientists, social scientists, and policymakers should more thoroughly evaluate whether current study and management of artificial aquatic systems is based on the actual ecological condition of these systems, or judged differently, due to artificiality, and consider resultant possible changes in goals for these systems. The emerging recognition and study of artificial aquatic systems presents an exciting and important opportunity for science and society.
Irrigation ditches are ubiquitous features of water networks in rural and urban settings in drylands, and are thus potentially important habitats within the modern hydroscape. The habitat value of ditches and other artificial systems depends on whether these systems respond to local and watershed-scale land use in similar ways to natural features, or whether artificial origin inherently constrains a system's ecological condition. The ditches and creeks of Bishop, California are fed by water from the same minimally developed watershed on the Eastern slope of the Sierra Nevada Mountains, and so served to test whether artificial and natural waters in the same watershed setting and with shared water can provide similar habitat. We sampled benthic macroinvertebrates at 52 sites within the town, stratified by substrate and season. Communities varied by substrate and season as expected, but did not differ significantly between artificial and natural streams. Instead, both types of streams changed as water flowed from undeveloped desert through town, suggesting that irrigation ditches respond to local urbanization in much the same way that natural streams do. Differences in finer-scale spatial structure of community similarity suggest that community assembly processes may differ between natural and artificial channels, but potential mechanisms for these differences are unclear. This study demonstrates that artificial aquatic systems may have substantial ecological value, and suggests that the poor condition of many artificial aquatic systems may reflect stressful watershed settings rather than something intrinsic to their artificiality.
The drainage ditches of the North Carolina Coastal Plain do not merely degrade wetlands; they themselves have ecological structural characteristics of wetlands. We surveyed 32 agricultural, freeway, and forested ditch reaches across this region for hydrologic indicators, soil organic matter, and plants. All showed some hydrologic indicators and had some soil organic matter, with easterly, swampy forests having the most, though with substantial variation across all and few significant differences between types. All had hydrophytic herbaceous plant communities in the sense of at least half their percent cover belonging to obligate, facultative wetland, or facultative taxa. These herbaceous communities differed significantly across site types (F=3.25, d.f.= 2, p=0.001), and responded to both landscape-level factors like nearby development coverage and local-level factors like apparent mowing. Sample sites were not well mapped in well-used federal aquatic databases; the National Hydrography Dataset only included one on a “CanalDitch” flow line, and the National Wetlands Inventory only included two within “partially drained/ditched” areas, and none as individual “excavated” features. Others were mis-categorized, but neither database included any highway sampling sites. Despite this limited information about extent, variation and management impact suggests that human potential to impact wetland structure of these manmade aquatic ecosystems throughout the North Carolina Coastal Plain, and beyond, could be large.
Artificial lakes are a dominant aquatic ecosystem type, but the processes controlling their condition are under-explored. Here we use structural equations modeling to compare the formation of algal blooms and associated water quality issues in 1,045 artificial and 870 natural lakes in the United States using the U.S. Environmental Protection Agency’s National Lakes Assessment data. We compare chemical and physical measurements associated with water quality and the relationships between them, and find that the processes are significantly different between natural and artificial lakes, in a way that suggests impacts of interference with thermal stratification through dam management in reservoirs. However, both the overall processes and the distributions of the data are roughly similar between the two origin types, and between 2007 and 2012 sample years. Artificial lakes are lakes, and process-based explorations of their behavior can help us better know management options.
Taken together, this dissertation examines an artificial version of each of the major aquatic ecosystem types: stream, wetland, and lake. It examines the processes controlling their ecological condition with increasing intricacy with each chapter, and finds ways that artificial aquatic ecosystems are both similar to and different from natural ones. This dissertation provides a new way of looking at the constraints and opportunities that artificial waterbodies afford those in charge of them and interested in their conservation potential.
Item Open Access Electric Power Plant Water Use in North Carolina: Forced Evaporation and Emission Controls(2010-04-30T13:51:18Z) Morton, VictoriaThe link between water use and electricity generation is very strong and largely omitted from the public policies aimed at sustainable generation of electricity. Electricity is required for treating and pumping water to its destination, and water is required for electricity generation at thermoelectric power plants for cooling purposes, and for the operation of environmental control devices that reduce air emissions. North Carolina is ranked 9th in the United States for electricity total net production, according to the Energy Information Administration. Thermoelectric power freshwater withdrawals far outstrip all other water withdrawal categories; by the year 2000, thermoelectric power freshwater withdrawals were approaching 8,000 million gallons per day, and as the population continues to grow in North Carolina, that number can only be expected to increase. They make some of the largest water withdrawals in the state of North Carolina, but they only consume approximately 3% of the water they intake. The consumptive use percentage of 3% is misleading because it doesn’t take into account forced evaporation. As mentioned previously, power plants require intake water to use for cooling purposes in the electricity generation process. The withdrawn cooling waters, once run through the plant, are returned to rivers/lakes at a higher temperature than the ambient water temperature. This higher temperature water causes additional evaporation (forced evaporation) from the river/lake. Forced evaporation should be of particular concern to North Carolina due to the severe droughts that have occurred in the region in recent history which threaten energy production as well as other water uses (ex. drinking water supply). In this project we find that forced evaporation represents an average 22% increase in power plant water consumption in North Carolina, when compared to water consumption occurring during electricity generation on-site. We also look at the impact that air emission controls have on the plants water consumption. If carbon emissions are required to be controlled in the future, then water use at all power plants will increase, on average, approximately 5%. The water lost to forced evaporation and emissions controls will add additional strain to power plants located in drought prone regions.Item Open Access Flows of Water and Wildlife in KAZA(2020-04-24) Morris, Jannette; Garcia, Gabriella; Lee, Ga-onThe Okavango Delta is the largest inland delta in the world and is an important region for southern African wildlife and biodiversity, and also a major source of regional tourism. The headwaters of the basin and the majority of its water resources are located upstream in the Angolan highlands, which have historically remained undeveloped. Angola has recently expressed an interest in developing the rivers of the upstream basin to support the economic and health needs of Angola’s growing population. This master’s project focused on trying to predict how new infrastructure development might change surface water distribution throughout the region, and by extension, wildlife movement in this region. We developed a water balance model to show how changes in upstream storage and water diversions would alter flows and flood extent at a key downstream location where the Okavango flattens out and spills into its characteristic and seasonal floodplain. For the wildlife movement, we focused on elephant movement in Bwabwata National Park in Namibia. Our analysis is a first step in helping inform the development and conservation planning in the region.Item Open Access Foreign Aid Allocation and Impact: A Sub-National Analysis of Malawi(2013-04-15) De, RajlakshmiThis project estimates the first sub-national model of foreign aid allocation and impact. Newly geocoded aid project data from Malawi is used in combination with multiple rounds of living standards data to predict the allocation of health aid, water aid, and education aid. In addition, the impacts of the three aid categories are detected using both instrumentation and propensity score matching methods to adjust for aid being allocated non-randomly. The three allocation models varied greatly with respect to the significant predictive covariates of diarrhea incidence, geographic region, and rural setting, but other aid allocation was a positive predictor in all three models such that areas receiving health aid were likely to also receive substantial water aid and education aid. A significant, positive effect of health aid on decreasing disease severity and a significant, positive effect of water aid on decreasing diarrhea incidence were found through both instrumentation and propensity score matching. An appropriate instrument for education aid could not be determined, but propensity score matching methods found a positive effect of education aid on school enrollment. These results suggest that foreign aid plays a useful role in poverty alleviation in Malawi and that governments should use information about local disease severity, diarrhea incidence, and school enrollment to allocate different aid types more efficiently.
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