Browsing by Author "Brown, TJ"

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Solid-state and dynamic solution behavior of a cationic, two-coordinate gold(I) π-allene complex

Brown, TJ; Sugie, A; Dickens, MG; Widenhoefer, RA (Organometallics, 2010-10-11)

The cationic gold π-allene complex {[P(t-Bu)2o-biphenyl] Au[η2-H2C=C=C(CH3)2]} +SbF6- was isolated in 98% yield from reaction of 3-methyl-1,2-butadiene with a mixture of [P(t-Bu)2o-biphenyl]AuCl and AgSbF6 and was characterized ...