Browsing by Subject "Amination"
Now showing items 1-3 of 3
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Analyzing site selectivity in Rh2(esp)2-catalyzed intermolecular C-H amination reactions.
(J Am Chem Soc, 2014-04-16)Predicting site selectivity in C-H bond oxidation reactions involving heteroatom transfer is challenged by the small energetic differences between disparate bond types and the subtle interplay of steric and electronic effects ... -
Nitrogen–Heteroatom Bond Enabled Synthesis of Pharmacologically Valuable Aminoarenes via Aryne and Aryl-Zinc Intermediates
(2017)Aminoarenes are common structural features in pharmaceuticals and biologically relevant scaffolds, motivating continued development of strategies to facilitate their synthesis. Canonical approaches to aryl amination rely ... -
Platinum(II)-catalyzed intermolecular hydroamination of monosubstituted allenes with secondary alkylamines.
(Chem Commun (Camb), 2010-03-14)A 1:1 mixture of (dppf)PtCl(2) and AgOTf (5 mol%) catalyzed the intermolecular hydroamination of monosubstituted allenes with secondary alkylamines at 80 degrees C to form allylic amines in good yield with selective formation ...
