Browsing by Subject "Catalysis"
Now showing items 1-5 of 5
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Analyzing site selectivity in Rh2(esp)2-catalyzed intermolecular C-H amination reactions.
(J Am Chem Soc, 2014-04-16)Predicting site selectivity in C-H bond oxidation reactions involving heteroatom transfer is challenged by the small energetic differences between disparate bond types and the subtle interplay of steric and electronic effects ... -
Elucidating solvent contributions to solution reactions with ab initio QM/MM methods.
(J Phys Chem B, 2010-03-04)Computer simulations of reaction processes in solution in general rely on the definition of a reaction coordinate and the determination of the thermodynamic changes of the system along the reaction coordinate. The reaction ... -
Inkless microcontact printing on SAMs of Boc- and TBS-protected thiols.
(Nano Lett, 2010-01)We report a new inkless catalytic muCP technique that achieves accurate, fast, and complete pattern reproduction on SAMs of Boc- and TBS-protected thiols immobilized on gold using a polyurethane-acrylate stamp functionalized ... -
Platinum(II)-catalyzed intermolecular hydroamination of monosubstituted allenes with secondary alkylamines.
(Chem Commun (Camb), 2010-03-14)A 1:1 mixture of (dppf)PtCl(2) and AgOTf (5 mol%) catalyzed the intermolecular hydroamination of monosubstituted allenes with secondary alkylamines at 80 degrees C to form allylic amines in good yield with selective formation ... -
Utilization of Nano-Catalysts for Green Electric Power Generation
(2015)Nano-structures were investigated for the advancement of energy conversion technology because of their enhanced catalytic, thermal, and physiochemical interfacial properties and increased solar absorption. Hydrogen is a ...
