The Theory and Modeling of Solar Cells Based on Semiconducting Quantum Dots
Quantum dots (QDs) are promising building block materials for many emerging energy-harvesting applications. We theoretically investigated the influences of the QD-QD (CdTe-CdSe) charge transfer rates and mechanisms on QD solar cells power conversion efficiencies using multi-level modeling methods including the first principle quantum chemistry calculations of QD electronic and charge transfer properties and the kinetic modeling of solar cell performances.
We developed tight-binding electronic structure models to explore the QD electronic properties, and the charge transfer kinetics including their dependences on QD sizes and QD surface-to-surface distance. We found that the QD-QD charge transfer rates follow the non-adiabatic rate expression by Marcus. The QD-QD electronic coupling strength decays exponentially as the QD surface-to-surface distance increases. The QD-QD charge transfer rates generally increase (decay) as the acceptor (donor) QD radius increases. We found that the TS coupling mechanism can dominate the QD-QD coupling over the TB coupling. The difference between the TS and TB coupling size dependences results in a dominance switch between the TS and TB charge transfer mechanisms in the QD dyad as the QD sizes grow.
We further explored the use of an external charge to modulate the QD-QD coupling strength and the coupling mechanism. We found that a positively charged group in the bridge strengthens the D-A coupling for all QD sizes. A negatively charged group in the bridge causes the D-A coupling reduction in large QDs. For small QDs, the D-A coupling variation induced by the negative charge depends on the QD sizes. Compared to the neutral bridge, we found that through-solvent and through-bridge mechanisms switch their dominance at smaller (larger) QD sizes for the positively (negatively) charged group in the molecular bridge.
Using the computed charge transfer rates, we explored the power conversion efficiencies of QD solar cells based on QD dyads and QD triads. We found that the external and internal power conversion quantum efficiencies are significantly enhanced by introducing a third QD between the donor and acceptor QDs. The improvements in the efficiencies can be further enhanced by tuning the band-edge energy offset of the middle-position QD from its neighbors.
Quantum Chemitry Simulation
This work is licensed under a Creative Commons Attribution-Noncommercial-No Derivative Works 3.0 United States License.
Rights for Collection: Duke Dissertations