Show simple item record

NMR methods for characterizing the pore structures and hydrogen storage properties of microporous carbons.

dc.contributor.author Anderson, Robert J
dc.contributor.author McNicholas, Thomas P
dc.contributor.author Kleinhammes, Alfred
dc.contributor.author Wang, Anmiao
dc.contributor.author Liu, Jie
dc.contributor.author Wu, Yue
dc.coverage.spatial United States
dc.date.accessioned 2011-06-21T17:26:25Z
dc.date.issued 2010-06-30
dc.identifier http://www.ncbi.nlm.nih.gov/pubmed/20524615
dc.identifier.uri https://hdl.handle.net/10161/4054
dc.description.abstract (1)H NMR spectroscopy is used to investigate a series of microporous activated carbons derived from a poly(ether ether ketone) (PEEK) precursor with varying amounts of burnoff (BO). In particular, properties relevant to hydrogen storage are evaluated such as pore structure, average pore size, uptake, and binding energy. High-pressure NMR with in situ H(2) loading is employed with H(2) pressure ranging from 100 Pa to 10 MPa. An N(2)-cooled cryostat allows for NMR isotherm measurements at both room temperature ( approximately 290 K) and 100 K. Two distinct (1)H NMR peaks appear in the spectra which represent the gaseous H(2) in intergranular pores and the H(2) residing in micropores. The chemical shift of the micropore peak is observed to evolve with changing pressure, the magnitude of this effect being correlated to the amount of BO and therefore the structure. This is attributed to the different pressure dependence of the amount of adsorbed and non-adsorbed molecules within micropores, which experience significantly different chemical shifts due to the strong distance dependence of the ring current effect. In pores with a critical diameter of 1.2 nm or less, no pressure dependence is observed because they are not wide enough to host non-adsorbed molecules; this is the case for samples with less than 35% BO. The largest estimated pore size that can contribute to the micropore peak is estimated to be around 2.4 nm. The total H(2) uptake associated with pores of this size or smaller is evaluated via a calibration of the isotherms, with the highest amount being observed at 59% BO. Two binding energies are present in the micropores, with the lower, more dominant one being on the order of 5 kJ mol(-1) and the higher one ranging from 7 to 9 kJ mol(-1).
dc.language eng
dc.language.iso en_US
dc.publisher American Chemical Society (ACS)
dc.relation.ispartof J Am Chem Soc
dc.relation.isversionof 10.1021/ja9109924
dc.title NMR methods for characterizing the pore structures and hydrogen storage properties of microporous carbons.
dc.title.alternative
dc.type Journal article
duke.contributor.id Liu, Jie|0230555
dc.description.version Version of Record
duke.date.pubdate 2010-6-30
duke.description.issue 25
duke.description.volume 132
dc.relation.journal Journal of the American Chemical Society
pubs.author-url http://www.ncbi.nlm.nih.gov/pubmed/20524615
pubs.begin-page 8618
pubs.end-page 8626
pubs.issue 25
pubs.organisational-group Chemistry
pubs.organisational-group Duke
pubs.organisational-group Trinity College of Arts & Sciences
pubs.publication-status Published
pubs.volume 132
dc.identifier.eissn 1520-5126
duke.contributor.orcid Liu, Jie|0000-0003-0451-6111


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record