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Total synthesis of cyanolide A and confirmation of its absolute configuration.

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Date
2010-06-18
Authors
Kim, Hyoungsu
Hong, Jiyong
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Abstract
The tandem allylic oxidation/oxa-Michael reaction promoted by the gem-disubstituent effect and the 2-methyl-6-nitrobenzoic anhydride (MNBA)-mediated dimerization were explored for the efficient and facile synthesis of cyanolide A.
Type
Journal article
Subject
Anhydrides
Animals
Glycosylation
Macrolides
Molecular Structure
Nitrobenzoates
Oxidation-Reduction
Schistosoma
Permalink
https://hdl.handle.net/10161/4106
Published Version (Please cite this version)
10.1021/ol101022z
Publication Info
Kim, Hyoungsu; & Hong, Jiyong (2010). Total synthesis of cyanolide A and confirmation of its absolute configuration. Org Lett, 12(12). pp. 2880-2883. 10.1021/ol101022z. Retrieved from https://hdl.handle.net/10161/4106.
This is constructed from limited available data and may be imprecise. To cite this article, please review & use the official citation provided by the journal.
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Scholars@Duke

Hong

Jiyong Hong

Professor of Chemistry
Research in the Hong group focuses on using chemical tools, in particular small molecules, to understand the signaling pathways in biology. We synthesize biologically interesting natural products and screen small molecule libraries to identify modulators of biological processes. Then, we explore their modes of action in order to investigate intracellular signaling pathways and identify novel targets for drug design. In addition, we design and develop unique and efficient synthetic strategies tha
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