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Platinum(II)-catalyzed intermolecular hydroamination of monosubstituted allenes with secondary alkylamines.
Abstract
A 1:1 mixture of (dppf)PtCl(2) and AgOTf (5 mol%) catalyzed the intermolecular hydroamination
of monosubstituted allenes with secondary alkylamines at 80 degrees C to form allylic
amines in good yield with selective formation of the E-diastereomer.
Type
Journal articlePermalink
https://hdl.handle.net/10161/4122Published Version (Please cite this version)
10.1039/b925859kPublication Info
(2010). Platinum(II)-catalyzed intermolecular hydroamination of monosubstituted allenes with
secondary alkylamines. Chem Commun (Camb), 46(10). pp. 1712-1714. 10.1039/b925859k. Retrieved from https://hdl.handle.net/10161/4122.This is constructed from limited available data and may be imprecise. To cite this
article, please review & use the official citation provided by the journal.
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Show full item recordScholars@Duke
Ross A. Widenhoefer
Professor of Chemistry
Research in the Widenhoefer group is directed toward the development and mechanistic
analysis of new organotransition metal-catalyzed transformations for application in
the synthesis of functionalized organic molecules. In particular, our group has a
long-standing interest in the functionalization of C–C multiple bonds with carbon
and heteroatom nucleophiles catalyzed by electrophilic late transition metal complexes,
with a recent focus on the synthetic and mechanistic aspect of gold(I) pi-acti
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