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Platinum(II)-catalyzed intermolecular hydroamination of monosubstituted allenes with secondary alkylamines.

dc.contributor.author Toups, Kristina L
dc.contributor.author Widenhoefer, Ross A
dc.coverage.spatial England
dc.date.accessioned 2011-06-21T17:27:14Z
dc.date.issued 2010-03-14
dc.identifier http://www.ncbi.nlm.nih.gov/pubmed/20177625
dc.identifier.uri https://hdl.handle.net/10161/4122
dc.description.abstract A 1:1 mixture of (dppf)PtCl(2) and AgOTf (5 mol%) catalyzed the intermolecular hydroamination of monosubstituted allenes with secondary alkylamines at 80 degrees C to form allylic amines in good yield with selective formation of the E-diastereomer.
dc.language eng
dc.language.iso en_US
dc.publisher Royal Society of Chemistry (RSC)
dc.relation.ispartof Chem Commun (Camb)
dc.relation.isversionof 10.1039/b925859k
dc.subject Alkadienes
dc.subject Amination
dc.subject Amines
dc.subject Catalysis
dc.subject Platinum
dc.subject Stereoisomerism
dc.title Platinum(II)-catalyzed intermolecular hydroamination of monosubstituted allenes with secondary alkylamines.
dc.title.alternative
dc.type Journal article
duke.contributor.id Widenhoefer, Ross A|0198528
dc.description.version Version of Record
duke.date.pubdate 2010-00-00
duke.description.issue 10
duke.description.volume 46
dc.relation.journal Chemical Communications
pubs.author-url http://www.ncbi.nlm.nih.gov/pubmed/20177625
pubs.begin-page 1712
pubs.end-page 1714
pubs.issue 10
pubs.organisational-group Chemistry
pubs.organisational-group Duke
pubs.organisational-group Trinity College of Arts & Sciences
pubs.publication-status Published
pubs.volume 46
dc.identifier.eissn 1364-548X


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