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Probing Mechanical Activation of Covalent Chemistry in Crosslinked Polymer Gels

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Date
2013
Author
Wang, Yifei
Advisor
Craig, Stephen L
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Abstract

Toughness, the measure of how much energy a material can absorb before rupture, is an important property of materials. It has been demonstrated that the toughness of a single polymer chain of <italic>gem</italic>-dihalocyclopropane (<italic>g</italic>DHC) functionalized polybutadiene (PB) is increased dramatically over PB alone, due to the mechanically triggered electrocyclic ring opening reaction of <italic>g</italic>DHC into 2,3-dibromoalkenes. This thesis explores whether this molecular mechanical property can also be manifested in bulk material properties. Crosslinked <italic>gem</italic>-dichlorocyclopropane (<italic>g</italic>DCC) embedded PB polymers were swollen in various solvents, and the resulting gels were mechanically deformed under tensile stress. Young's modulus and fracture toughness were compared among PBs with <italic>g</italic>DCC incorporated in the backbones and/or crosslinking positions. The results showed that the incorporation of <italic>g</italic>DCC does not measurably increase the fracture toughness of the crosslinked polymer gels. Neither NMR nor FT-IR characterization of the post-test samples revealed detectable activation of the <italic>g</italic>DCC in the crosslinked PB. Further experiments will be focused on optimizing the polymer structure and testing methods to more effectively transfer the macroscopic force to the mechanophore in the material and continuing exploring the correlation between molecular responses and changes in macroscopic properties.

Type
Master's thesis
Department
Chemistry
Subject
Chemistry
Polymer chemistry
Organic chemistry
crosslinked polybutadiene
fracture toughness
gem-dichlorocyclopropane
mechanical activation
mechanophore
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https://hdl.handle.net/10161/7288
Citation
Wang, Yifei (2013). Probing Mechanical Activation of Covalent Chemistry in Crosslinked Polymer Gels. Master's thesis, Duke University. Retrieved from https://hdl.handle.net/10161/7288.
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