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Probing Mechanical Activation of Covalent Chemistry in Crosslinked Polymer Gels

dc.contributor.advisor Craig, Stephen L Wang, Yifei 2013-05-13T15:37:26Z 2013-05-13T15:37:26Z 2013
dc.description.abstract <p>Toughness, the measure of how much energy a material can absorb before rupture, is an important property of materials. It has been demonstrated that the toughness of a single polymer chain of <italic>gem</italic>-dihalocyclopropane (<italic>g</italic>DHC) functionalized polybutadiene (PB) is increased dramatically over PB alone, due to the mechanically triggered electrocyclic ring opening reaction of <italic>g</italic>DHC into 2,3-dibromoalkenes. This thesis explores whether this molecular mechanical property can also be manifested in bulk material properties. Crosslinked <italic>gem</italic>-dichlorocyclopropane (<italic>g</italic>DCC) embedded PB polymers were swollen in various solvents, and the resulting gels were mechanically deformed under tensile stress. Young's modulus and fracture toughness were compared among PBs with <italic>g</italic>DCC incorporated in the backbones and/or crosslinking positions. The results showed that the incorporation of <italic>g</italic>DCC does not measurably increase the fracture toughness of the crosslinked polymer gels. Neither NMR nor FT-IR characterization of the post-test samples revealed detectable activation of the <italic>g</italic>DCC in the crosslinked PB. Further experiments will be focused on optimizing the polymer structure and testing methods to more effectively transfer the macroscopic force to the mechanophore in the material and continuing exploring the correlation between molecular responses and changes in macroscopic properties.</p>
dc.subject Chemistry
dc.subject Polymer chemistry
dc.subject Organic chemistry
dc.subject crosslinked polybutadiene
dc.subject fracture toughness
dc.subject gem-dichlorocyclopropane
dc.subject mechanical activation
dc.subject mechanophore
dc.title Probing Mechanical Activation of Covalent Chemistry in Crosslinked Polymer Gels
dc.type Master's thesis
dc.department Chemistry

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