Isotopic imprints of mountaintop mining contaminants.
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Mountaintop mining (MTM) is the primary procedure for surface coal exploration within the central Appalachian region of the eastern United States, and it is known to contaminate streams in local watersheds. In this study, we measured the chemical and isotopic compositions of water samples from MTM-impacted tributaries and streams in the Mud River watershed in West Virginia. We systematically document the isotopic compositions of three major constituents: sulfur isotopes in sulfate (δ(34)SSO4), carbon isotopes in dissolved inorganic carbon (δ(13)CDIC), and strontium isotopes ((87)Sr/(86)Sr). The data show that δ(34)SSO4, δ(13)CDIC, Sr/Ca, and (87)Sr/(86)Sr measured in saline- and selenium-rich MTM impacted tributaries are distinguishable from those of the surface water upstream of mining impacts. These tracers can therefore be used to delineate and quantify the impact of MTM in watersheds. High Sr/Ca and low (87)Sr/(86)Sr characterize tributaries that originated from active MTM areas, while tributaries from reclaimed MTM areas had low Sr/Ca and high (87)Sr/(86)Sr. Leaching experiments of rocks from the watershed show that pyrite oxidation and carbonate dissolution control the solute chemistry with distinct (87)Sr/(86)Sr ratios characterizing different rock sources. We propose that MTM operations that access the deeper Kanawha Formation generate residual mined rocks in valley fills from which effluents with distinctive (87)Sr/(86)Sr and Sr/Ca imprints affect the quality of the Appalachian watersheds.
SubjectCarbon Compounds, Inorganic
Water Pollutants, Chemical
Published Version (Please cite this version)10.1021/es4012959
Publication InfoDi Giulio, RT; Dwyer, Gary; Lindberg, TT; Merola, BR; Ruhl, Laura S; Vengosh, Avner; ... White, A (2013). Isotopic imprints of mountaintop mining contaminants. Environ Sci Technol, 47(17). pp. 10041-10048. 10.1021/es4012959. Retrieved from https://hdl.handle.net/10161/8304.
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Instructor in Earth and Ocean Sciences
Dwyer's experience lies in the development of tracers and indicators of environmental change, and their application to modern and ancient environmental systems. Research areas include paleoceanography, paleoclimatology, carbonate sedimentology, marine geology and environmental geochemistry.
Professor of Earth and Ocean Sciences
My research aims to link environmental geochemistry and isotope hydrology in order to trace the sources and mechanisms of water contamination and relationships with human health. Current research includes global changes of the chemical and isotopic compositions of water resources due to human intervention and contamination, salinization of water resources in the Middle East and Northern Africa, naturally occurring contaminants (arsenic, fluoride, boron) and radioactivity in water resources, the
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