Boron and strontium isotopic characterization of coal combustion residuals: validation of new environmental tracers.
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In the U.S., coal fired power plants produce over 136 million tons of coal combustion residuals (CCRs) annually. CCRs are enriched in toxic elements, and their leachates can have significant impacts on water quality. Here we report the boron and strontium isotopic ratios of leaching experiments on CCRs from a variety of coal sources (Appalachian, Illinois, and Powder River Basins). CCR leachates had a mostly negative δ(11)B, ranging from -17.6 to +6.3‰, and (87)Sr/(86)Sr ranging from 0.70975 to 0.71251. Additionally, we utilized these isotopic ratios for tracing CCR contaminants in different environments: (1) the 2008 Tennessee Valley Authority (TVA) coal ash spill affected waters; (2) CCR effluents from power plants in Tennessee and North Carolina; (3) lakes and rivers affected by CCR effluents in North Carolina; and (4) porewater extracted from sediments in lakes affected by CCRs. The boron isotopes measured in these environments had a distinctive negative δ(11)B signature relative to background waters. In contrast (87)Sr/(86)Sr ratios in CCRs were not always exclusively different from background, limiting their use as a CCR tracer. This investigation demonstrates the validity of the combined geochemical and isotopic approach as a unique and practical identification method for delineating and evaluating the environmental impact of CCRs.
Published Version (Please cite this version)10.1021/es503746v
Publication InfoDwyer, Gary; Hower, JC; Hsu-Kim, Heileen; Ruhl, Laura S; & Vengosh, Avner (2014). Boron and strontium isotopic characterization of coal combustion residuals: validation of new environmental tracers. Environ Sci Technol, 48(24). pp. 14790-14798. 10.1021/es503746v. Retrieved from https://hdl.handle.net/10161/9347.
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Instructor in Earth and Ocean Sciences
Dwyer's experience lies in the development of tracers and indicators of environmental change, and their application to modern and ancient environmental systems. Research areas include paleoceanography, paleoclimatology, carbonate sedimentology, marine geology and environmental geochemistry.
Professor in the Department of Civil and Environmental Engineering
Professor Heileen (Helen) Hsu-Kim is an environmental engineer who specializes in environmental aquatic chemistry and geochemistry. Her research tackles problems related to pollutant metals and the biogeochemical processes that alter their distribution in water, soil, and air. The applications of this work include environmental remediation technologies, the impacts of energy production on water resources, global environmental health, and the environmental implications and applications of nanotec
Professor of Earth and Ocean Sciences
My research aims to link environmental geochemistry and isotope hydrology in order to trace the sources and mechanisms of water contamination and relationships with human health. Current research includes global changes of the chemical and isotopic compositions of water resources due to human intervention and contamination, salinization of water resources in the Middle East and Northern Africa, naturally occurring contaminants (arsenic, fluoride, boron) and radioactivity in water resources, the
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