Solid-state and dynamic solution behavior of a cationic, two-coordinate gold(I) π-allene complex
dc.contributor.author | Brown, TJ | |
dc.contributor.author | Sugie, A | |
dc.contributor.author | Dickens, MG | |
dc.contributor.author | Widenhoefer, RA | |
dc.date.accessioned | 2011-06-21T17:27:12Z | |
dc.date.issued | 2010-10-11 | |
dc.description.abstract | The cationic gold π-allene complex {[P(t-Bu)2o-biphenyl] Au[η2-H2C=C=C(CH3)2]} +SbF6- was isolated in 98% yield from reaction of 3-methyl-1,2-butadiene with a mixture of [P(t-Bu)2o-biphenyl]AuCl and AgSbF6 and was characterized by X-ray crystallography and variable-temperature NMR spectroscopy. These studies revealed preferential binding of gold to the less substituted C=C bond of the allene in both the solid state and solution and also revealed fluxional behavior consistent with π-face exchange of the allene ligand via an η1-C2 allene intermediate or transition state. © 2010 American Chemical Society. | |
dc.description.version | Version of Record | |
dc.identifier.eissn | 1520-6041 | |
dc.identifier.issn | 0276-7333 | |
dc.identifier.uri | ||
dc.language.iso | en_US | |
dc.publisher | American Chemical Society (ACS) | |
dc.relation.ispartof | Organometallics | |
dc.relation.isversionof | 10.1021/om100688t | |
dc.relation.journal | Organometallics | |
dc.title | Solid-state and dynamic solution behavior of a cationic, two-coordinate gold(I) π-allene complex | |
dc.title.alternative | ||
dc.type | Journal article | |
duke.date.pubdate | 2010-10-11 | |
duke.description.issue | 19 | |
duke.description.volume | 29 | |
pubs.begin-page | 4207 | |
pubs.end-page | 4209 | |
pubs.issue | 19 | |
pubs.organisational-group | Chemistry | |
pubs.organisational-group | Duke | |
pubs.organisational-group | Trinity College of Arts & Sciences | |
pubs.publication-status | Published | |
pubs.volume | 29 |