Gold(I)-Catalyzed Amination of Allylic Alcohols with Cyclic Ureas and Related Nucleophiles

dc.contributor.author

Mukherjee, Paramita

dc.contributor.author

Widenhoefer, Ross A

dc.date.accessioned

2011-06-21T17:27:11Z

dc.date.available

2011-06-21T17:27:11Z

dc.date.issued

2010

dc.description.abstract

A 1:1 mixture of [P(t-Bu)(2)-o-biphenyl]AuCl and AgSbF6 catalyzes the Intermolecular amination of allylic alcohols with 1-methylimidazolidin-2-one and related nucleophiles that, in the case of gamma-unsubstituted or gamma-methyl-substituted allylic alcohols, occurs with high gamma-regloselectivity and syn-stereoselectivity.

dc.description.version

Version of Record

dc.identifier.citation

Mukherjee,Paramita;Widenhoefer,Ross A.. 2010. Gold(I)-Catalyzed Amination of Allylic Alcohols with Cyclic Ureas and Related Nucleophiles. Organic letters 12(6): 1184-1187.

dc.identifier.issn

1523-7060

dc.identifier.uri

https://hdl.handle.net/10161/4110

dc.language.iso

en_US

dc.publisher

American Chemical Society (ACS)

dc.relation.isversionof

10.1021/ol902923e

dc.relation.journal

Organic letters

dc.subject

catalyzed direct amination

dc.subject

titanium(iv) isopropoxide

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neutral

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conditions

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secondary-amines

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palladium

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allylation

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complexes

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efficient

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alkylation

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ligands

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chemistry, organic

dc.title

Gold(I)-Catalyzed Amination of Allylic Alcohols with Cyclic Ureas and Related Nucleophiles

dc.title.alternative
dc.type

Other article

duke.date.pubdate

2010-3-19

duke.description.issue

6

duke.description.volume

12

pubs.begin-page

1184

pubs.end-page

1187

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