Radium and barium removal through blending hydraulic fracturing fluids with acid mine drainage.

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2014-01-21

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Abstract

Wastewaters generated during hydraulic fracturing of the Marcellus Shale typically contain high concentrations of salts, naturally occurring radioactive material (NORM), and metals, such as barium, that pose environmental and public health risks upon inadequate treatment and disposal. In addition, fresh water scarcity in dry regions or during periods of drought could limit shale gas development. This paper explores the possibility of using alternative water sources and their impact on NORM levels through blending acid mine drainage (AMD) effluent with recycled hydraulic fracturing flowback fluids (HFFFs). We conducted a series of laboratory experiments in which the chemistry and NORM of different mix proportions of AMD and HFFF were examined after reacting for 48 h. The experimental data combined with geochemical modeling and X-ray diffraction analysis suggest that several ions, including sulfate, iron, barium, strontium, and a large portion of radium (60-100%), precipitated into newly formed solids composed mainly of Sr barite within the first ∼ 10 h of mixing. The results imply that blending AMD and HFFF could be an effective management practice for both remediation of the high NORM in the Marcellus HFFF wastewater and beneficial utilization of AMD that is currently contaminating waterways in northeastern U.S.A.

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10.1021/es403852h

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Kondash, Andrew J, Nathaniel R Warner, Ori Lahav and Avner Vengosh (2014). Radium and barium removal through blending hydraulic fracturing fluids with acid mine drainage. Environ Sci Technol, 48(2). pp. 1334–1342. 10.1021/es403852h Retrieved from https://hdl.handle.net/10161/8302.

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Scholars@Duke

Vengosh

Avner Vengosh

Nicholas Distinguished Professor of Environmental Quality

Avner Vengosh is a Distinguished Professor and Nicholas Chair of Environmental Quality at the Nicholas School of the Environment. He is the chair of the Division of  Earth and Climate Sciences. Professor Vengosh and his team have studied the energy-water nexus, conducting pioneer research on the impact of hydraulic fracturing and coal ash disposal on the quantity and quality of water resources in the U.S. and China. He has also investigated the sources and mechanisms of water contamination in numerous countries across the globe, including salinity and radioactivity in the Middle East, uranium in India, fluoride in Eastern Africa, arsenic in Vietnam, and hexavalent chromium in North Carolina and China. As part of these studies, his team has developed novel geochemical and isotopic tracers that are used as fingerprints to delineate the sources of water contamination and evaluate potential risks for human health. Currently, his team is engaged in studying phosphate rocks geochemistry and the impact of fertilizers on soil and water quality, unconventional sources of critical raw materials, and potential environmental effects of lithium mining from hard rocks and brines. He is a Fellow of the Geological Society of America (GSA) and International Association of Geochemistry (IAGC). In 2019, 2020 and 2021 he was recognized as one of the Web of Science Highly Cited Researchers. He serves as an Editor of GeoHealth and on the editorial board of the journal Environmental Science and Technology. He has published 171 scientific papers in leading international journals. His recent cross-disciplinary book “Water Quality Impacts of the Energy-Water Nexus” (Cambridge University Press, 2020) provides an integrated assessment of the different scientific and policy tools around the energy-water nexus. It focuses on how water use, and wastewater and waste solids produced from fossil fuel energy production affect water quality and quantity. Summarizing cutting edge research, the book describes the scientific methods for detecting contamination sources in the context of policy and regulations.


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