Inorganic carbon speciation and fluxes in the Congo River

Seasonal variations in inorganic carbon chemistry and associated fluxes from the Congo River were investigated at Brazzaville-Kinshasa. Small seasonal variation in dissolved inorganic carbon (DIC) was found in contrast with discharge-correlated changes in pH, total alkalinity (TA), carbonate species, and dissolved organic carbon (DOC). DIC was almost always greater than TA due to the importance of CO2, the sum of dissolved CO2 and carbonic acid, as a result of low pH. Organic acids in DOC contributed 11-61% of TA and had a strong titration effect on water pH and carbonate speciation. The CO2 and bicarbonate fluxes accounted for ~57% and 43% of the DIC flux, respectively. Congo River surface water released CO2 at a rate of ~109 mol m^-2 yr^-1. The basin-wide DIC yield was ~8.84 × 10⁴ mol km^-2 yr^-1. The discharge normalized DIC flux to the ocean amounted to 3.11 × 10¹¹ mol yr^-1. The DOC titration effect on the inorganic carbon system may also be important on a global scale for regulating carbon fluxes in rivers. Key Points The carbonate chemistry near the Congo River mouth is comprehensively studied Organic acids have a titration effect on the inorganic carbon system Surface CO2 and inorganic carbon fluxes to the ocean are characterized ©2013. American Geophysical Union. All Rights Reserved.