Mercury Sourcing and Sequestration in Weathering Profiles at Six Critical Zone Observatories

Loading...
Thumbnail Image

Date

2018-10-01

Journal Title

Journal ISSN

Volume Title

Repository Usage Stats

45
views
30
downloads

Citation Stats

Abstract

©2018. American Geophysical Union. All Rights Reserved. Mercury sequestration in regolith (soils + weathered bedrock) is an important ecosystem service of the critical zone. This has largely remained unexplored, due to the difficulty of sample collection and the assumption that Hg is predominantly sequestered within surface soils (here we define as 0–0.3 m). We measured Hg concentrations and inventories in weathering profiles at six Critical Zone Observatories (CZOs): Boulder Creek in the Front Range of Colorado, Calhoun in the South Carolina Piedmont, Eel River in coastal northern California, Luquillo in the tropical montane forest of Puerto Rico, Shale Hills of the valley and ridges of central Pennsylvania, and Southern Sierra in the Sierra Nevada range of California. Surface soils had higher Hg concentrations than the deepest regolith samples, except for Eel River, which had lower Hg concentrations in surface soils compared to regolith. Using Ti normalization, CZOs with <12% rock-derived Hg (Boulder Creek, Calhoun, and Southern Sierra) had Hg peaks between 1.5 and 8.0 m in depth. At CZOs with >50% rock-derived Hg, Eel River Hg concentrations and pools were greatest at >4.0 m in the weathering profile, while Luquillo and Shale Hills had peaks at the surface that diminished within 1.0 m of the surface. Hg and total organic C were only significantly correlated in regolith at Luquillo and Shale Hills CZOs, suggesting that Hg sorption to organic matter may be less dominant than clays or Fe(II) sulfides in deeper regolith. Our results demonstrate the importance of Hg sequestration in deep regolith, below typical soil sampling depths.

Department

Description

Provenance

Citation

Published Version (Please cite this version)

10.1029/2018GB005974

Publication Info

Richardson, JB, AA Aguirre, HL Buss, A Toby O'Geen, X Gu, DM Rempe and DDB Richter (2018). Mercury Sourcing and Sequestration in Weathering Profiles at Six Critical Zone Observatories. Global Biogeochemical Cycles, 32(10). pp. 1542–1555. 10.1029/2018GB005974 Retrieved from https://hdl.handle.net/10161/21236.

This is constructed from limited available data and may be imprecise. To cite this article, please review & use the official citation provided by the journal.

Scholars@Duke

Richter

Daniel D. Richter

Professor in the Division of Earth and Climate Science

Richter’s research and teaching links soils with ecosystems and the wider environment, most recently Earth scientists’ Critical Zone.  He focuses on how humanity is transforming Earth’s soils from natural to human-natural systems, specifically how land-uses alter soil processes and properties on time scales of decades, centuries, and millennia.  Richter's book, Understanding Soil Change (Cambridge University Press), co-authored with his former PhD student Daniel Markewitz (Professor at University of Georgia), explores a legacy of soil change across the Southern Piedmont of North America, from the acidic soils of primary hardwood forests that covered the region until 1800, through the marked transformations affected by long-cultivated cotton, to contemporary soils of rapidly growing and intensively managed pine forests.  Richter and colleagues work to expand the concept of soil as the full biogeochemical weathering system of the Earth’s crust, ie, the Earth’s belowground Critical Zone, which can be tens of meters deep.  The research examines decadal to millennial changes in the chemistry and cycling of soil C, N, P, Ca, K, Mg, and trace elements B, Fe, Mn, Cu, Be, Zr, and Zn across full soil profiles as deep at 30-m.  Since 1988, Richter has worked at and directed the Long-Term Calhoun Soil-Ecosystem Experiment (LTSE) in the Piedmont of South Carolina, a collaborative study with the USDA Forest Service that quantifies how soils form as natural bodies and are transformed by human action, and a study that has grown to become an international model for such long-term soil and ecosystem studies.  In 2005, Richter and students initiated the first comprehensive international inventory project of the world’s LTSEs, using an advanced-format website that has networked metadata from 250 LTSEs.  The LTSEs project has held three workshops at Duke University, NCSU's Center for Environmental Farming Systems, and the USDA Forest Service's Calhoun Experimental Forest and Coweeta Hydrologic Laboratory, hosting representatives from Africa, Asia, Australia, Europe, and the Americas.  Richter's 60-year old Long Term Calhoun Soil and Ecosystem Experiment is linked to similar experiments and platforms around the world via the ‘Long-Term Soil-Ecosystem Experiments Global Inventory’, assembled by Dan Richter, Pete Smith, and Mike Hofmockel."He is an active member of the International Commission on Stratigraphy’s Working Group on the Anthropocene.  Richter has written in the peer-reviewed literature about all of these projects, and in November 2014 his soils research at the Calhoun and his soils teaching were featured in Science magazine.


Unless otherwise indicated, scholarly articles published by Duke faculty members are made available here with a CC-BY-NC (Creative Commons Attribution Non-Commercial) license, as enabled by the Duke Open Access Policy. If you wish to use the materials in ways not already permitted under CC-BY-NC, please consult the copyright owner. Other materials are made available here through the author’s grant of a non-exclusive license to make their work openly accessible.