Dynamics and fluctuations of minimally structured glass formers.

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2024-05

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Abstract

The mean-field theory (MFT) of simple structural glasses, which is exact in the limit of infinite spatial dimensions, d→∞, offers theoretical insight as well as quantitative predictions about certain features of d=3 systems. In order to more systematically relate the behavior of physical systems to MFT, however, various finite-d effects need to be accounted for. Although some efforts along this direction have already been undertaken, theoretical and technical challenges hinder progress. A general approach to sidestep many of these difficulties consists of simulating minimally structured models whose behavior smoothly converges to that described by the MFT as d increases, so as to permit a controlled dimensional extrapolation. Using this approach, we here extract the small fluctuations around the dynamical MFT captured by a standard liquid-state observable, the non-Gaussian parameter α_{2}. The results provide insight into the physical origin of these fluctuations as well as a quantitative reference with which to compare observations for more realistic glass formers.

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Published Version (Please cite this version)

10.1103/physreve.109.054905

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Charbonneau, Patrick, Yi Hu and Peter K Morse (2024). Dynamics and fluctuations of minimally structured glass formers. Physical review. E, 109(5-1). p. 054905. 10.1103/physreve.109.054905 Retrieved from https://hdl.handle.net/10161/32195.

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Scholars@Duke

Charbonneau

Patrick Charbonneau

Professor of Chemistry

Professor Charbonneau studies soft matter. His work combines theory and simulation to understand the glass problem, protein crystallization, microphase formation, and colloidal assembly in external fields.


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