Gold(I)-Catalyzed Amination of Allylic Alcohols with Cyclic Ureas and Related Nucleophiles

Mukherjee, Paramita ; Widenhoefer, Ross
2010
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Organic letters
AMER CHEMICAL SOC
 

Abstract:

A 1:1 mixture of [P(t-Bu)(2)-o-biphenyl]AuCl and AgSbF6 catalyzes the Intermolecular amination of allylic alcohols with 1-methylimidazolidin-2-one and related nucleophiles that, in the case of gamma-unsubstituted or gamma-methyl-substituted allylic alcohols, occurs with high gamma-regloselectivity and syn-stereoselectivity.

Citation:

Mukherjee,Paramita;Widenhoefer,Ross A.. 2010. Gold(I)-Catalyzed Amination of Allylic Alcohols with Cyclic Ureas and Related Nucleophiles. Organic letters 12(6): 1184-1187.
Citable Link to This Page: http://hdl.handle.net/10161/4110
Published Version: doi:10.1021/ol902923e

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