Mean-Field Caging in a Random Lorentz Gas.

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2021-06-07

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Abstract

The random Lorentz gas (RLG) is a minimal model of both percolation and glassiness, which leads to a paradox in the infinite-dimensional, d → ∞ limit: the localization transition is then expected to be continuous for the former and discontinuous for the latter. As a putative resolution, we have recently suggested that, as d increases, the behavior of the RLG converges to the glassy description and that percolation physics is recovered thanks to finite-d perturbative and nonperturbative (instantonic) corrections [Biroli et al. Phys. Rev. E 2021, 103, L030104]. Here, we expand on the d → ∞ physics by considering a simpler static solution as well as the dynamical solution of the RLG. Comparing the 1/d correction of this solution with numerical results reveals that even perturbative corrections fall out of reach of existing theoretical descriptions. Comparing the dynamical solution with the mode-coupling theory (MCT) results further reveals that, although key quantitative features of MCT are far off the mark, it does properly capture the discontinuous nature of the d → ∞ RLG. These insights help chart a path toward a complete description of finite-dimensional glasses.

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10.1021/acs.jpcb.1c02067

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Biroli, Giulio, Patrick Charbonneau, Yi Hu, Harukuni Ikeda, Grzegorz Szamel and Francesco Zamponi (2021). Mean-Field Caging in a Random Lorentz Gas. The journal of physical chemistry. B, 125(23). pp. 6244–6254. 10.1021/acs.jpcb.1c02067 Retrieved from https://hdl.handle.net/10161/24975.

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Charbonneau

Patrick Charbonneau

Professor of Chemistry

Professor Charbonneau studies soft matter. His work combines theory and simulation to understand the glass problem, protein crystallization, microphase formation, and colloidal assembly in external fields.


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